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[N'-(4-Dec-yloxy-2-oxido-benzyl-idene)-3-hy-droxy-2-naphtho-hydrazidato-κ(3)N,O,O']di-methyl-tin(IV): crystal structure and Hirshfeld surface analysis

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  • Siti Nadiah Binti Mohd Rosely
  • Rusnah Syahila Duali Hussen
  • See Mun Lee
  • Nathan R. Halcovitch
  • Mukesh M. Jotani
  • Edward R. T. Tiekink
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<mark>Journal publication date</mark>1/03/2017
<mark>Journal</mark>Acta Crystallographica Section E: Crystallographic Communications
Issue number3
Volume73
Number of pages7
Pages (from-to)390-396
Publication StatusPublished
<mark>Original language</mark>English

Abstract

The title diorganotin compound, [Sn(CH3)2(C28H32N2O4)], features a distorted SnC2NO2 coordination geometry almost inter-mediate between ideal trigonal-bipyramidal and square-pyramidal. The dianionic Schiff base ligand coordinates in a tridentate fashion via two alkoxide O and hydrazinyl N atoms; an intra-molecular hy-droxy-O-H⋯N(hydrazin-yl) hydrogen bond is noted. The alk-oxy chain has an all-trans conformation, and to the first approximation, the mol-ecule has local mirror symmetry relating the two Sn-bound methyl groups. Supra-molecular layers sustained by imine-C-H⋯O(hy-droxy), π-π [between dec-yloxy-substituted benzene rings with an inter-centroid separation of 3.7724 (13) Å], C-H⋯π(arene) and C-H⋯π(chelate ring) inter-actions are formed in the crystal; layers stack along the c axis with no directional inter-actions between them. The presence of C-H⋯π(chelate ring) inter-actions in the crystal is clearly evident from an analysis of the calculated Hirshfeld surface.