Research output: Contribution to Journal/Magazine › Journal article › peer-review
<mark>Journal publication date</mark> | 2014 |
---|---|
<mark>Journal</mark> | RSC Advances |
Issue number | 4 |
Volume | 4 |
Number of pages | 8 |
Pages (from-to) | 1996-2003 |
Publication Status | Published |
<mark>Original language</mark> | English |
We report on the synthesis and the properties of N,N,N',N'-tetramethyl-N '',N ''-pentamethyleneguanidinium bis(trifluoromethylsulfonyl)imide (PipGuan-TFSI). The cation of this novel ionic liquid combines guanidinium and piperidinium structural elements. We tested it for its viscosity, ion conductivity, and also for its thermal and electrochemical stability. Furthermore, a 0.5 M solution of lithium TFSI in PipGuan-TFSI was tested as an electrolyte for Li-ion batteries. These experiments included cycles of Li deposition/dissolution on stainless steel and (de) intercalation into/from LiFePO4 electrodes. The tests involving LiFePO4 cathodes were performed at various C-rates and temperatures for a better quantitative comparison to other electrolyte systems. We discuss in how far PipGuan-TFSI successfully combines the advantages of guanidinium and piperidinium ionic liquids for battery electrolyte applications.