The near field dynamics of transitional buoyant reactive jets established on noncircular geometries, including a rectangular nozzle with an aspect ratio of 2 : I and a square nozzle with the same cross-sectional area, are investigated by three-dimensional spatial direct numerical simulations. Without applying external perturbations at the inflow boundary, large vortical structures develop naturally in the flow field due to buoyancy effects. Simulation results and analysis describe the details and clarify mechanisms of vortex dynamics of the noncircular buoyant reactive jets. The interaction between density gradients and gravity initiates the flow vorticity. Among the major vorticity transport terms, the gravitational term mainly promotes flow vorticity in the cross-streamwise direction. For the baroclinic torque, it can either create or destroy flow vorticity depending on the local flow structure. The vortex stretching term has different effects on the streamwise and cross-streamwise vorticity. Streamwise vorticity is mainly created by vortex stretching, while this term can either create or destroy cross-streamwise vorticity. Under the coupling effects of buoyancy and noncircular nozzle geometry, three-dimensional vortex interactions lead to the transitional behavior of the reactive jets. Simulations also show that the rectangular jet is more vortical than the square jet. The rectangular jet has a stronger tendency of transition to turbulence at the downstream due to the aspect ratio effect. Mean flow property calculations show that the rectangular buoyant reactive jet has a higher entrainment rate than its square counterpart.