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Al-27 double rotation two-dimensional spin diffusion NMR: Complete unambiguous assignment of aluminium sites in 9Al(2)O(3) center dot 2B(2)O(3)

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Published
  • I. Hung
  • A. P. Howes
  • Tiit Anupõld
  • A. Samoson
  • D. Massiot
  • Mark E. Smith
  • S. P. Brown
  • Ray Dupree
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<mark>Journal publication date</mark>2006
<mark>Journal</mark>Chemical Physics Letters
Issue number1-3
Volume432
Number of pages5
Pages (from-to)152-156
Publication StatusPublished
<mark>Original language</mark>English

Abstract

High-resolution two-dimensional Al-27 spin diffusion NMR spectra of 9Al(2)O(3) (.) 2B(2)O(3) recorded under double rotation for different mixing times are presented. The two crystallographically distinct pentahedral Al sites are distinguished by the presence or absence of correlation peaks with neighboring tetrahedral sites.