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The synthesis of a pyridine-: N -oxide isophthalamide rotaxane utilizing supplementary amide hydrogen bond interactions

Research output: Contribution to journalJournal article

Published
<mark>Journal publication date</mark>7/09/2016
<mark>Journal</mark>Organic and Biomolecular Chemistry
Issue number33
Volume14
Number of pages10
Pages (from-to)7972-7981
<mark>State</mark>Published
Early online date1/08/16
<mark>Original language</mark>English

Abstract

The synthesis of a pyridine-N-oxide containing rotaxane, not requiring an additional ionic template, has been achieved in 32% yield. Successful rotaxane formation is dependent upon the structure of the isophthalamide macrocycle used, an observation which has been rationalised by a combination of NMR spectroscopy, X-ray crystallography and computational modelling.

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© Royal Society of Chemistry 2016