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A 12-fold ThSi2 interpenetrated network utilizing a glycine-based pseudopeptidic ligand

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A 12-fold ThSi2 interpenetrated network utilizing a glycine-based pseudopeptidic ligand. / Loukopoulos, Edward; Michail, Alexandra; Kostakis, George E.
In: Crystals, Vol. 8, No. 1, 47, 18.01.2018.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Loukopoulos, E, Michail, A & Kostakis, GE 2018, 'A 12-fold ThSi2 interpenetrated network utilizing a glycine-based pseudopeptidic ligand', Crystals, vol. 8, no. 1, 47. https://doi.org/10.3390/cryst8010047

APA

Loukopoulos, E., Michail, A., & Kostakis, G. E. (2018). A 12-fold ThSi2 interpenetrated network utilizing a glycine-based pseudopeptidic ligand. Crystals, 8(1), Article 47. https://doi.org/10.3390/cryst8010047

Vancouver

Loukopoulos E, Michail A, Kostakis GE. A 12-fold ThSi2 interpenetrated network utilizing a glycine-based pseudopeptidic ligand. Crystals. 2018 Jan 18;8(1):47. doi: 10.3390/cryst8010047

Author

Loukopoulos, Edward ; Michail, Alexandra ; Kostakis, George E. / A 12-fold ThSi2 interpenetrated network utilizing a glycine-based pseudopeptidic ligand. In: Crystals. 2018 ; Vol. 8, No. 1.

Bibtex

@article{19cf1788f5e241f5a238392446b48e1b,
title = "A 12-fold ThSi2 interpenetrated network utilizing a glycine-based pseudopeptidic ligand",
abstract = "We report the synthesis and characterization of a 3D Cu(II) coordination polymer, [Cu3 (L1)2 (H2 O)8 ]·8H2 O (1), with the use of a glycine-based tripodal pseudopeptidic ligand (H3 L1 = N,N′,N′′ -tris(carboxymethyl)-1,3,5-benzenetricarboxamide or trimesoyl-tris-glycine). This compound presents the first example of a 12-fold interpenetrated ThSi2 (ths) net. We attempt to justify the unique topology of 1 through a systematic comparison of the synthetic parameters in all reported structures with H3 L1 and similar tripodal pseudopeptidic ligands. We additionally explore the catalytic potential of 1 in the A3 coupling reaction for the synthesis of propargylamines. The compound acts as a very good heterogeneous catalyst with yields up to 99% and loadings as low as 3 mol %.",
keywords = "12-fold, A coupling, Catalysis, Coordination polymer, Copper, Interpenetration",
author = "Edward Loukopoulos and Alexandra Michail and Kostakis, {George E.}",
year = "2018",
month = jan,
day = "18",
doi = "10.3390/cryst8010047",
language = "English",
volume = "8",
journal = "Crystals",
issn = "2073-4352",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "1",

}

RIS

TY - JOUR

T1 - A 12-fold ThSi2 interpenetrated network utilizing a glycine-based pseudopeptidic ligand

AU - Loukopoulos, Edward

AU - Michail, Alexandra

AU - Kostakis, George E.

PY - 2018/1/18

Y1 - 2018/1/18

N2 - We report the synthesis and characterization of a 3D Cu(II) coordination polymer, [Cu3 (L1)2 (H2 O)8 ]·8H2 O (1), with the use of a glycine-based tripodal pseudopeptidic ligand (H3 L1 = N,N′,N′′ -tris(carboxymethyl)-1,3,5-benzenetricarboxamide or trimesoyl-tris-glycine). This compound presents the first example of a 12-fold interpenetrated ThSi2 (ths) net. We attempt to justify the unique topology of 1 through a systematic comparison of the synthetic parameters in all reported structures with H3 L1 and similar tripodal pseudopeptidic ligands. We additionally explore the catalytic potential of 1 in the A3 coupling reaction for the synthesis of propargylamines. The compound acts as a very good heterogeneous catalyst with yields up to 99% and loadings as low as 3 mol %.

AB - We report the synthesis and characterization of a 3D Cu(II) coordination polymer, [Cu3 (L1)2 (H2 O)8 ]·8H2 O (1), with the use of a glycine-based tripodal pseudopeptidic ligand (H3 L1 = N,N′,N′′ -tris(carboxymethyl)-1,3,5-benzenetricarboxamide or trimesoyl-tris-glycine). This compound presents the first example of a 12-fold interpenetrated ThSi2 (ths) net. We attempt to justify the unique topology of 1 through a systematic comparison of the synthetic parameters in all reported structures with H3 L1 and similar tripodal pseudopeptidic ligands. We additionally explore the catalytic potential of 1 in the A3 coupling reaction for the synthesis of propargylamines. The compound acts as a very good heterogeneous catalyst with yields up to 99% and loadings as low as 3 mol %.

KW - 12-fold

KW - A coupling

KW - Catalysis

KW - Coordination polymer

KW - Copper

KW - Interpenetration

U2 - 10.3390/cryst8010047

DO - 10.3390/cryst8010047

M3 - Journal article

AN - SCOPUS:85041126030

VL - 8

JO - Crystals

JF - Crystals

SN - 2073-4352

IS - 1

M1 - 47

ER -