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A [2]catenane displaying pirouetting motion triggered by debenzylation and locked by chloride anion recognition

Research output: Contribution to journalJournal article

Published

Journal publication date07/2011
JournalChemistry - A European Journal
Journal number28
Volume17
Number of pages5
Pages7734-7738
Original languageEnglish

Abstract

Chloride locks the rings: Debenzylation of a chloride-templated N-benzyl pyridinium catenane, allows for a 180° “pirouetting” of the rings in the resulting neutral pyridyl catenane (see scheme). The catenane may be returned to its original co-conformation by chloride recognition as evidenced in solution and in the solid state.