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A ferrocene functionalized rotaxane host system capable of the electrochemical recognition of chloride

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A ferrocene functionalized rotaxane host system capable of the electrochemical recognition of chloride. / Evans, Nicholas H.; Beer, Paul D.
In: Organic and Biomolecular Chemistry , Vol. 9, No. 1, 07.01.2011, p. 92-100.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

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Evans NH, Beer PD. A ferrocene functionalized rotaxane host system capable of the electrochemical recognition of chloride. Organic and Biomolecular Chemistry . 2011 Jan 7;9(1):92-100. doi: 10.1039/c0ob00458h

Author

Evans, Nicholas H. ; Beer, Paul D. / A ferrocene functionalized rotaxane host system capable of the electrochemical recognition of chloride. In: Organic and Biomolecular Chemistry . 2011 ; Vol. 9, No. 1. pp. 92-100.

Bibtex

@article{5cdced9456244e329448ac2dcbfdf886,
title = "A ferrocene functionalized rotaxane host system capable of the electrochemical recognition of chloride",
abstract = "A ferrocene appended rotaxane is prepared by chloride anion templation and ring closing metathesis. Upon removal of the chloride template, the rotaxane is demonstrated to be selective for chloride over more basic oxoanions by H-1 NMR spectroscopy and electrochemistry, in marked contrast to an acyclic analogue - the first example of a solution based redox-active interlocked host system capable of the electrochemical recognition of anions.",
keywords = "ANION-TEMPLATED FORMATION, CONDUCTING POLYMETALLOROTAXANES, MOLECULAR SHUTTLES, DIRECTED SYNTHESIS, RECEPTORS, POLYROTAXANES, CYCLODEXTRIN, ION, COMPLEXATION, CATENANES",
author = "Evans, {Nicholas H.} and Beer, {Paul D.}",
year = "2011",
month = jan,
day = "7",
doi = "10.1039/c0ob00458h",
language = "English",
volume = "9",
pages = "92--100",
journal = "Organic and Biomolecular Chemistry ",
issn = "1477-0520",
publisher = "Royal Society of Chemistry",
number = "1",

}

RIS

TY - JOUR

T1 - A ferrocene functionalized rotaxane host system capable of the electrochemical recognition of chloride

AU - Evans, Nicholas H.

AU - Beer, Paul D.

PY - 2011/1/7

Y1 - 2011/1/7

N2 - A ferrocene appended rotaxane is prepared by chloride anion templation and ring closing metathesis. Upon removal of the chloride template, the rotaxane is demonstrated to be selective for chloride over more basic oxoanions by H-1 NMR spectroscopy and electrochemistry, in marked contrast to an acyclic analogue - the first example of a solution based redox-active interlocked host system capable of the electrochemical recognition of anions.

AB - A ferrocene appended rotaxane is prepared by chloride anion templation and ring closing metathesis. Upon removal of the chloride template, the rotaxane is demonstrated to be selective for chloride over more basic oxoanions by H-1 NMR spectroscopy and electrochemistry, in marked contrast to an acyclic analogue - the first example of a solution based redox-active interlocked host system capable of the electrochemical recognition of anions.

KW - ANION-TEMPLATED FORMATION

KW - CONDUCTING POLYMETALLOROTAXANES

KW - MOLECULAR SHUTTLES

KW - DIRECTED SYNTHESIS

KW - RECEPTORS

KW - POLYROTAXANES

KW - CYCLODEXTRIN

KW - ION

KW - COMPLEXATION

KW - CATENANES

U2 - 10.1039/c0ob00458h

DO - 10.1039/c0ob00458h

M3 - Journal article

VL - 9

SP - 92

EP - 100

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

SN - 1477-0520

IS - 1

ER -