A redox-active [3]rotaxane capable of binding and electrochemically sensing chloride and sulfate anions

Chemistry

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https://doi.org/10.1039/c1cc13247d
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Keywords

MOLECULAR SHUTTLES, AQUEOUS-MEDIA, ROTAXANES, POLYROTAXANES, CATENANES, MACHINES, MOTORS, HOST

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A redox-active [3]rotaxane capable of binding and electrochemically sensing chloride and sulfate anions. / Evans, Nicholas H.; Serpell, Christopher J.; Beer, Paul D.
In: Chemical Communications, Vol. 47, No. 31, 21.08.2011, p. 8775-8777.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Bibtex

@article{87e41769a4304b28affc3b45344d2cc3,

title = "A redox-active [3]rotaxane capable of binding and electrochemically sensing chloride and sulfate anions",

abstract = "A ferrocene functionalised redox-active [3]rotaxane which contains two interlocked anion recognition sites has been prepared by chloride anion templation. With chloride two equivalents of anion are bound, one in each of the interlocked cavities, while sulfate forms a 1 : 1 stoichimetric sandwich type complex; the rotaxane can also electrochemically sense the two anions in acetonitrile.",

keywords = "MOLECULAR SHUTTLES, AQUEOUS-MEDIA, ROTAXANES, POLYROTAXANES, CATENANES, MACHINES, MOTORS, HOST",

author = "Evans, {Nicholas H.} and Serpell, {Christopher J.} and Beer, {Paul D.}",

year = "2011",

month = aug,

day = "21",

doi = "10.1039/c1cc13247d",

language = "English",

volume = "47",

pages = "8775--8777",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "31",

}

RIS

TY - JOUR

T1 - A redox-active [3]rotaxane capable of binding and electrochemically sensing chloride and sulfate anions

AU - Evans, Nicholas H.

AU - Serpell, Christopher J.

AU - Beer, Paul D.

PY - 2011/8/21

Y1 - 2011/8/21

N2 - A ferrocene functionalised redox-active [3]rotaxane which contains two interlocked anion recognition sites has been prepared by chloride anion templation. With chloride two equivalents of anion are bound, one in each of the interlocked cavities, while sulfate forms a 1 : 1 stoichimetric sandwich type complex; the rotaxane can also electrochemically sense the two anions in acetonitrile.

AB - A ferrocene functionalised redox-active [3]rotaxane which contains two interlocked anion recognition sites has been prepared by chloride anion templation. With chloride two equivalents of anion are bound, one in each of the interlocked cavities, while sulfate forms a 1 : 1 stoichimetric sandwich type complex; the rotaxane can also electrochemically sense the two anions in acetonitrile.

KW - MOLECULAR SHUTTLES

KW - AQUEOUS-MEDIA

KW - ROTAXANES

KW - POLYROTAXANES

KW - CATENANES

KW - MACHINES

KW - MOTORS

KW - HOST

UR - http://www.scopus.com/inward/record.url?scp=79960957827&partnerID=8YFLogxK

U2 - 10.1039/c1cc13247d

DO - 10.1039/c1cc13247d

M3 - Journal article

VL - 47

SP - 8775

EP - 8777

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 31

ER -

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