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A Sm(II)-mediated cascade approach to Dibenzoindolo[3,2-b]carbazoles: synthesis and evaluation

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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A Sm(II)-mediated cascade approach to Dibenzoindolo[3,2-b]carbazoles: synthesis and evaluation. / Levick, Matthew T.; Grace, Iain; Dai, Sheng-Yao et al.
In: Organic Letters, Vol. 16, No. 8, 18.04.2014, p. 2292-2295.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Levick, MT, Grace, I, Dai, S-Y, Kasch, N, Muryn, C, Lambert, C, Turner, ML & Procter, DJ 2014, 'A Sm(II)-mediated cascade approach to Dibenzoindolo[3,2-b]carbazoles: synthesis and evaluation', Organic Letters, vol. 16, no. 8, pp. 2292-2295. https://doi.org/10.1021/ol500841b

APA

Levick, M. T., Grace, I., Dai, S-Y., Kasch, N., Muryn, C., Lambert, C., Turner, M. L., & Procter, D. J. (2014). A Sm(II)-mediated cascade approach to Dibenzoindolo[3,2-b]carbazoles: synthesis and evaluation. Organic Letters, 16(8), 2292-2295. https://doi.org/10.1021/ol500841b

Vancouver

Levick MT, Grace I, Dai S-Y, Kasch N, Muryn C, Lambert C et al. A Sm(II)-mediated cascade approach to Dibenzoindolo[3,2-b]carbazoles: synthesis and evaluation. Organic Letters. 2014 Apr 18;16(8):2292-2295. doi: 10.1021/ol500841b

Author

Levick, Matthew T. ; Grace, Iain ; Dai, Sheng-Yao et al. / A Sm(II)-mediated cascade approach to Dibenzoindolo[3,2-b]carbazoles : synthesis and evaluation. In: Organic Letters. 2014 ; Vol. 16, No. 8. pp. 2292-2295.

Bibtex

@article{8533e33394b0447889ebd67c22c0ebf0,
title = "A Sm(II)-mediated cascade approach to Dibenzoindolo[3,2-b]carbazoles: synthesis and evaluation",
abstract = "Previously unstudied dibenzoindolo[3,2-b]carbazoles have been prepared by two-directional, phase tag-assisted synthesis utilizing a connective-Pummerer cyclization and a SmI2-mediated tag cleavage-cyclization cascade. The use of a phase tag allows us to exploit unstable intermediates that would otherwise need to be avoided. The novel materials were characterized by X-ray, cyclic voltammetry, UV-vis spectroscopy, TGA, and DSC. Preliminary studies on the performance of OFET devices are also described.",
keywords = "DIHYDROPYRROLOINDOLEDIONE-BASED COPOLYMERS, CYCLATIVE-CAPTURE STRATEGY, SOLID-PHASE EXTRACTION, TAG-ASSISTED SYNTHESIS, THIN-FILM TRANSISTORS, ORGANIC ELECTRONICS, SAMARIUM(II) IODIDE, FLUOROUS SYNTHESIS, CARBONYL-COMPOUNDS, PUMMERER REACTION",
author = "Levick, {Matthew T.} and Iain Grace and Sheng-Yao Dai and Nicholas Kasch and Christopher Muryn and Colin Lambert and Turner, {Michael L.} and Procter, {David J.}",
note = "ACS AuthorChoice - Terms of Use CC-BY",
year = "2014",
month = apr,
day = "18",
doi = "10.1021/ol500841b",
language = "English",
volume = "16",
pages = "2292--2295",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "8",

}

RIS

TY - JOUR

T1 - A Sm(II)-mediated cascade approach to Dibenzoindolo[3,2-b]carbazoles

T2 - synthesis and evaluation

AU - Levick, Matthew T.

AU - Grace, Iain

AU - Dai, Sheng-Yao

AU - Kasch, Nicholas

AU - Muryn, Christopher

AU - Lambert, Colin

AU - Turner, Michael L.

AU - Procter, David J.

N1 - ACS AuthorChoice - Terms of Use CC-BY

PY - 2014/4/18

Y1 - 2014/4/18

N2 - Previously unstudied dibenzoindolo[3,2-b]carbazoles have been prepared by two-directional, phase tag-assisted synthesis utilizing a connective-Pummerer cyclization and a SmI2-mediated tag cleavage-cyclization cascade. The use of a phase tag allows us to exploit unstable intermediates that would otherwise need to be avoided. The novel materials were characterized by X-ray, cyclic voltammetry, UV-vis spectroscopy, TGA, and DSC. Preliminary studies on the performance of OFET devices are also described.

AB - Previously unstudied dibenzoindolo[3,2-b]carbazoles have been prepared by two-directional, phase tag-assisted synthesis utilizing a connective-Pummerer cyclization and a SmI2-mediated tag cleavage-cyclization cascade. The use of a phase tag allows us to exploit unstable intermediates that would otherwise need to be avoided. The novel materials were characterized by X-ray, cyclic voltammetry, UV-vis spectroscopy, TGA, and DSC. Preliminary studies on the performance of OFET devices are also described.

KW - DIHYDROPYRROLOINDOLEDIONE-BASED COPOLYMERS

KW - CYCLATIVE-CAPTURE STRATEGY

KW - SOLID-PHASE EXTRACTION

KW - TAG-ASSISTED SYNTHESIS

KW - THIN-FILM TRANSISTORS

KW - ORGANIC ELECTRONICS

KW - SAMARIUM(II) IODIDE

KW - FLUOROUS SYNTHESIS

KW - CARBONYL-COMPOUNDS

KW - PUMMERER REACTION

U2 - 10.1021/ol500841b

DO - 10.1021/ol500841b

M3 - Journal article

VL - 16

SP - 2292

EP - 2295

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 8

ER -