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A spin-trap study of the aqueous heterogeneous copolymerization of acrylonitrile and vinyl acetate.

Research output: Contribution to journalJournal article


Journal publication date1993
JournalEuropean Polymer Journal
Journal number2-3
Number of pages4
Original languageEnglish


Electron spin resonance spectroscopy has been used, in conjunction with the spin-trapping technique, to distinguish between the acrylonitrile and vinyl acetate propagating radicals. Employing this technique it has been possible to determine a value of kVAA/kAVA (ca 39). This value is in agreement with expectation for this system.