Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
}
TY - JOUR
T1 - A study of aerosol entrapment and the influence of wind speed, chamber design and foam density on polyurethane foam passive air samplers used for persistent organic pollutants.
AU - Chaemfa, Chakra
AU - Wild, Edward
AU - Davison, Brian
AU - Barber, Jonathan L.
AU - Jones, Kevin C.
PY - 2009
Y1 - 2009
N2 - Polyurethane foam disks are a cheap and versatile tool for sampling persistent organic pollutants (POPs) from the air in ambient, occupational and indoor settings. This study provides important background information on the ways in which the performance of these commonly used passive air samplers may be influenced by the key environmental variables of wind speed and aerosol entrapment. Studies were performed in the field, a wind tunnel and with microscopy techniques, to investigate deployment conditions and foam density influence on gas phase sampling rates (not obtained in this study) and aerosol trapping. The study showed: wind speed inside the sampler is greater on the upper side of the sampling disk than the lower side and tethered samplers have higher wind speeds across the upper and lower surfaces of the foam disk at a wind speed 4 m/s; particles are trapped on the foam surface and within the body of the foam disk; fine (<1 um) particles can form clusters of larger size inside the foam matrix. Whilst primarily designed to sample gas phase POPs, entrapment of particles ensures some sampling of particle bound POPs species, such as higher molecular weight PAHs and PCDD/Fs. Further work is required to investigate how quantitative such entrapment or sampling is under different ambient conditions, and with different aerosol sizes and types.
AB - Polyurethane foam disks are a cheap and versatile tool for sampling persistent organic pollutants (POPs) from the air in ambient, occupational and indoor settings. This study provides important background information on the ways in which the performance of these commonly used passive air samplers may be influenced by the key environmental variables of wind speed and aerosol entrapment. Studies were performed in the field, a wind tunnel and with microscopy techniques, to investigate deployment conditions and foam density influence on gas phase sampling rates (not obtained in this study) and aerosol trapping. The study showed: wind speed inside the sampler is greater on the upper side of the sampling disk than the lower side and tethered samplers have higher wind speeds across the upper and lower surfaces of the foam disk at a wind speed 4 m/s; particles are trapped on the foam surface and within the body of the foam disk; fine (<1 um) particles can form clusters of larger size inside the foam matrix. Whilst primarily designed to sample gas phase POPs, entrapment of particles ensures some sampling of particle bound POPs species, such as higher molecular weight PAHs and PCDD/Fs. Further work is required to investigate how quantitative such entrapment or sampling is under different ambient conditions, and with different aerosol sizes and types.
U2 - 10.1039/b823016a
DO - 10.1039/b823016a
M3 - Journal article
VL - 11
SP - 1135
EP - 1139
JO - Journal of Environmental Monitoring
JF - Journal of Environmental Monitoring
SN - 1464-0325
IS - 6
ER -