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  • SYNLETT Acid Sobralene-Correction

    Rights statement: © Georg Thieme Verlag Stuttgart · New York

    Accepted author manuscript, 492 KB, PDF document

    Embargo ends: 13/08/20

    Available under license: CC BY-NC: Creative Commons Attribution-NonCommercial 4.0 International License

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Acid-Catalysed Rearrangement of the Sandfly Pheromone Sobralene to Verticillenes, Consolidating its Relationship inter alia to the Taxanes and Phomactins

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<mark>Journal publication date</mark>1/10/2019
<mark>Journal</mark>SYNLETT
Issue number16
Volume30
Number of pages5
Pages (from-to)1899-1903
Publication statusPublished
Early online date13/08/19
Original languageEnglish

Abstract

The sex-aggregation pheromone sobralene produced by the sandfly Lutzomyia longipalpis is isomerised to verticillenes in the presence of mild acid, thereby providing credence to the proposal that sobralene is a likely shunt metabolite of the taxadiene synthase cascade.

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© Georg Thieme Verlag Stuttgart · New York