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Analysis of hydrogen storage in nanoporous materials for low carbon energy applications

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Analysis of hydrogen storage in nanoporous materials for low carbon energy applications. / Bimbo, Nuno; Ting, Valeska P.; Hruzewicz-Kolodziejczyk, Anna; Mays, Timothy J.

In: Faraday Discussions, Vol. 151, No. 1-2, 03.08.2011, p. 59-74.

Research output: Contribution to journalJournal article

Harvard

Bimbo, N, Ting, VP, Hruzewicz-Kolodziejczyk, A & Mays, TJ 2011, 'Analysis of hydrogen storage in nanoporous materials for low carbon energy applications', Faraday Discussions, vol. 151, no. 1-2, pp. 59-74. https://doi.org/10.1039/c0fd00010h

APA

Bimbo, N., Ting, V. P., Hruzewicz-Kolodziejczyk, A., & Mays, T. J. (2011). Analysis of hydrogen storage in nanoporous materials for low carbon energy applications. Faraday Discussions, 151(1-2), 59-74. https://doi.org/10.1039/c0fd00010h

Vancouver

Bimbo N, Ting VP, Hruzewicz-Kolodziejczyk A, Mays TJ. Analysis of hydrogen storage in nanoporous materials for low carbon energy applications. Faraday Discussions. 2011 Aug 3;151(1-2):59-74. https://doi.org/10.1039/c0fd00010h

Author

Bimbo, Nuno ; Ting, Valeska P. ; Hruzewicz-Kolodziejczyk, Anna ; Mays, Timothy J. / Analysis of hydrogen storage in nanoporous materials for low carbon energy applications. In: Faraday Discussions. 2011 ; Vol. 151, No. 1-2. pp. 59-74.

Bibtex

@article{a0dcf00afc3c4ad1aa13a8e1b08151f0,
title = "Analysis of hydrogen storage in nanoporous materials for low carbon energy applications",
abstract = "A robust, simple methodology for analysis of isotherms for the adsorption of fluids above their critical temperature onto nanostructured materials is presented. The analysis of hydrogen adsorption in a metal-organic framework is used as an example to illustrate the methodology, which allows the estimation of the absolute adsorption into nanoporous systems. Further advantages of employing this analysis are that adsorption systems can be described using a small number of parameters, and that excess and absolute isotherms can be extrapolated and used to predict adsorption behaviour at higher pressures and over different temperature ranges. Thermodynamic calculations, using the exact Clapeyron equation and the Clausius-Clapeyron approximation applied to the example dataset, are presented and compared. Conventional compression of hydrogen and adsorptive storage are evaluated, with an illustration of the pressure ranges in which adsorption facilitates storage of greater volumes of hydrogen than normal compression in the same operating conditions.",
keywords = "METAL-ORGANIC FRAMEWORKS, CARBIDE-DERIVED CARBONS, GAS-ADSORPTION, POROUS MATERIALS, HIGH-PRESSURE, POROSITY, SOLIDS, SCATTERING, ISOTHERMS, EQUATIONS",
author = "Nuno Bimbo and Ting, {Valeska P.} and Anna Hruzewicz-Kolodziejczyk and Mays, {Timothy J.}",
year = "2011",
month = aug,
day = "3",
doi = "10.1039/c0fd00010h",
language = "English",
volume = "151",
pages = "59--74",
journal = "Faraday Discussions",
issn = "1359-6640",
publisher = "ROYAL SOC CHEMISTRY",
number = "1-2",

}

RIS

TY - JOUR

T1 - Analysis of hydrogen storage in nanoporous materials for low carbon energy applications

AU - Bimbo, Nuno

AU - Ting, Valeska P.

AU - Hruzewicz-Kolodziejczyk, Anna

AU - Mays, Timothy J.

PY - 2011/8/3

Y1 - 2011/8/3

N2 - A robust, simple methodology for analysis of isotherms for the adsorption of fluids above their critical temperature onto nanostructured materials is presented. The analysis of hydrogen adsorption in a metal-organic framework is used as an example to illustrate the methodology, which allows the estimation of the absolute adsorption into nanoporous systems. Further advantages of employing this analysis are that adsorption systems can be described using a small number of parameters, and that excess and absolute isotherms can be extrapolated and used to predict adsorption behaviour at higher pressures and over different temperature ranges. Thermodynamic calculations, using the exact Clapeyron equation and the Clausius-Clapeyron approximation applied to the example dataset, are presented and compared. Conventional compression of hydrogen and adsorptive storage are evaluated, with an illustration of the pressure ranges in which adsorption facilitates storage of greater volumes of hydrogen than normal compression in the same operating conditions.

AB - A robust, simple methodology for analysis of isotherms for the adsorption of fluids above their critical temperature onto nanostructured materials is presented. The analysis of hydrogen adsorption in a metal-organic framework is used as an example to illustrate the methodology, which allows the estimation of the absolute adsorption into nanoporous systems. Further advantages of employing this analysis are that adsorption systems can be described using a small number of parameters, and that excess and absolute isotherms can be extrapolated and used to predict adsorption behaviour at higher pressures and over different temperature ranges. Thermodynamic calculations, using the exact Clapeyron equation and the Clausius-Clapeyron approximation applied to the example dataset, are presented and compared. Conventional compression of hydrogen and adsorptive storage are evaluated, with an illustration of the pressure ranges in which adsorption facilitates storage of greater volumes of hydrogen than normal compression in the same operating conditions.

KW - METAL-ORGANIC FRAMEWORKS

KW - CARBIDE-DERIVED CARBONS

KW - GAS-ADSORPTION

KW - POROUS MATERIALS

KW - HIGH-PRESSURE

KW - POROSITY

KW - SOLIDS

KW - SCATTERING

KW - ISOTHERMS

KW - EQUATIONS

U2 - 10.1039/c0fd00010h

DO - 10.1039/c0fd00010h

M3 - Journal article

VL - 151

SP - 59

EP - 74

JO - Faraday Discussions

JF - Faraday Discussions

SN - 1359-6640

IS - 1-2

ER -