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Blue rhenium tricarbonyl DPPZ complexes – low energy charge-transfer absorption at tissue-penetrating wavelengths

Research output: Contribution to journalJournal article

Published
<mark>Journal publication date</mark>28/10/2016
<mark>Journal</mark>Chemical Communications
Issue number84
Volume52
Number of pages4
Pages (from-to)12498-12501
Publication statusPublished
Early online date29/09/16
Original languageEnglish

Abstract

fac-[Re(CO)3(dppz)] complexes of amido ligands generated in situ under basic conditions display an intense (ε = 16460 L mol−1 cm−1) absorption band between 500–700 nm which are assigned to an n(amido,RNH–) → π* (dppz) inter-ligand charge transfer band offering an extraordinarily low energy charge separating absorption with potential for imaging and energy application.