Final published version
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Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Blue rhenium tricarbonyl DPPZ complexes – low energy charge-transfer absorption at tissue-penetrating wavelengths
AU - Coogan, Michael Peter
AU - Platts, James A.
PY - 2016/10/28
Y1 - 2016/10/28
N2 - fac-[Re(CO)3(dppz)] complexes of amido ligands generated in situ under basic conditions display an intense (ε = 16460 L mol−1 cm−1) absorption band between 500–700 nm which are assigned to an n(amido,RNH–) → π* (dppz) inter-ligand charge transfer band offering an extraordinarily low energy charge separating absorption with potential for imaging and energy application.
AB - fac-[Re(CO)3(dppz)] complexes of amido ligands generated in situ under basic conditions display an intense (ε = 16460 L mol−1 cm−1) absorption band between 500–700 nm which are assigned to an n(amido,RNH–) → π* (dppz) inter-ligand charge transfer band offering an extraordinarily low energy charge separating absorption with potential for imaging and energy application.
U2 - 10.1039/C6CC07125B
DO - 10.1039/C6CC07125B
M3 - Journal article
VL - 52
SP - 12498
EP - 12501
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 84
ER -