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  • Sweeney et al. revised Ni C-allylation

    Rights statement: This is the peer reviewed version of the following article: J. B. Sweeney, A. K. Ball, L. J. Smith, Chem. Eur. J. 2018, 24, 7354 which has been published in final form at http://onlinelibrary.wiley.com/doi/10.1002/chem.201801241/abstract This article may be used for non-commercial purposes in accordance With Wiley Terms and Conditions for self-archiving.

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Catalytic C-C Bond Formation Using a Simple Nickel Precatalyst System: Base- and Activator-Free Direct C-Allylation by Alcohols and Amines

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<mark>Journal publication date</mark>23/05/2018
<mark>Journal</mark>Chemistry - A European Journal
Issue number29
Volume24
Number of pages4
Pages (from-to)7354-7357
Publication statusPublished
Early online date13/03/18
Original languageEnglish

Abstract

A "totally catalytic" nickel(0)-mediated method for base-free direct alkylation of allyl alcohols and allyl amines is reported. The reaction is selective for monoallylation, uses an inexpensive NiII precatalyst system, and requires no activating reagents to be present.

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This is the peer reviewed version of the following article: J. B. Sweeney, A. K. Ball, L. J. Smith, Chem. Eur. J. 2018, 24, 7354 which has been published in final form at http://onlinelibrary.wiley.com/doi/10.1002/chem.201801241/abstract This article may be used for non-commercial purposes in accordance With Wiley Terms and Conditions for self-archiving.