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Catalytic inverse vulcanization

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Article number647
<mark>Journal publication date</mark>7/02/2019
<mark>Journal</mark>Nature Communications
Issue number1
Volume10
Number of pages9
Publication StatusPublished
<mark>Original language</mark>English

Abstract

The discovery of inverse vulcanization has allowed stable polymers to be made from elemental sulfur, an unwanted by-product of the petrochemicals industry. However, further development of both the chemistry and applications is handicapped by the restricted choice of cross-linkers and the elevated temperatures required for polymerisation. Here we report the catalysis of inverse vulcanization reactions. This catalytic method is effective for a wide range of crosslinkers reduces the required reaction temperature and reaction time, prevents harmful H 2 S production, increases yield, improves properties, and allows crosslinkers that would be otherwise unreactive to be used. Thus, inverse vulcanization becomes more widely applicable, efficient, eco-friendly and productive than the previous routes, not only broadening the fundamental chemistry itself, but also opening the door for the industrialization and broad application of these fascinating materials. © 2019, The Author(s).