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    Rights statement: This is the peer reviewed version of the following article: N. H. Evans, Chem. Eur. J. 2018, 24, 3101 which has been published in final form at http://onlinelibrary.wiley.com/doi/10.1002/chem.201704149/abstract This article may be used for non-commercial purposes in accordance With Wiley Terms and Conditions for self-archiving.

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Chiral catenanes and rotaxanes: fundamentals and emerging applications

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Chiral catenanes and rotaxanes: fundamentals and emerging applications. / Evans, Nicholas Henley.
In: Chemistry - A European Journal, Vol. 24, No. 13, 02.03.2018, p. 3101-3112.

Research output: Contribution to Journal/MagazineLiterature reviewpeer-review

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Evans NH. Chiral catenanes and rotaxanes: fundamentals and emerging applications. Chemistry - A European Journal. 2018 Mar 2;24(13):3101-3112. Epub 2017 Oct 20. doi: 10.1002/chem.201704149

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Evans, Nicholas Henley. / Chiral catenanes and rotaxanes : fundamentals and emerging applications. In: Chemistry - A European Journal. 2018 ; Vol. 24, No. 13. pp. 3101-3112.

Bibtex

@article{e85cc878c5224a38b3742a92ef8680cf,
title = "Chiral catenanes and rotaxanes: fundamentals and emerging applications",
abstract = "Molecular chirality provides a key challenge in host-guest recognition and other related chemical applications such as asymmetric catalysis. For a molecule to act as an efficient enantioselective receptor, it requires multi-point interactions between host and chiral guest, which may be achieved by an appropriate chiral 3D scaffold. As a consequence of their interlocked structure, catenanes and rotaxanes may present such a 3D scaffold, and can be chiral by inclusion of a classical chiral element and/or as a consequence of the mechanical bond. This Minireview presents illustrative examples of chiral [2]catenanes and [2]rotaxanes, and discusses where these molecules have been used in chemical applications such as chiral host-guest recognition and asymmetric catalysis.",
author = "Evans, {Nicholas Henley}",
note = "This is the peer reviewed version of the following article: N. H. Evans, Chem. Eur. J. 2018, 24, 3101 which has been published in final form at http://onlinelibrary.wiley.com/doi/10.1002/chem.201704149/abstract This article may be used for non-commercial purposes in accordance With Wiley Terms and Conditions for self-archiving.",
year = "2018",
month = mar,
day = "2",
doi = "10.1002/chem.201704149",
language = "English",
volume = "24",
pages = "3101--3112",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",
number = "13",

}

RIS

TY - JOUR

T1 - Chiral catenanes and rotaxanes

T2 - fundamentals and emerging applications

AU - Evans, Nicholas Henley

N1 - This is the peer reviewed version of the following article: N. H. Evans, Chem. Eur. J. 2018, 24, 3101 which has been published in final form at http://onlinelibrary.wiley.com/doi/10.1002/chem.201704149/abstract This article may be used for non-commercial purposes in accordance With Wiley Terms and Conditions for self-archiving.

PY - 2018/3/2

Y1 - 2018/3/2

N2 - Molecular chirality provides a key challenge in host-guest recognition and other related chemical applications such as asymmetric catalysis. For a molecule to act as an efficient enantioselective receptor, it requires multi-point interactions between host and chiral guest, which may be achieved by an appropriate chiral 3D scaffold. As a consequence of their interlocked structure, catenanes and rotaxanes may present such a 3D scaffold, and can be chiral by inclusion of a classical chiral element and/or as a consequence of the mechanical bond. This Minireview presents illustrative examples of chiral [2]catenanes and [2]rotaxanes, and discusses where these molecules have been used in chemical applications such as chiral host-guest recognition and asymmetric catalysis.

AB - Molecular chirality provides a key challenge in host-guest recognition and other related chemical applications such as asymmetric catalysis. For a molecule to act as an efficient enantioselective receptor, it requires multi-point interactions between host and chiral guest, which may be achieved by an appropriate chiral 3D scaffold. As a consequence of their interlocked structure, catenanes and rotaxanes may present such a 3D scaffold, and can be chiral by inclusion of a classical chiral element and/or as a consequence of the mechanical bond. This Minireview presents illustrative examples of chiral [2]catenanes and [2]rotaxanes, and discusses where these molecules have been used in chemical applications such as chiral host-guest recognition and asymmetric catalysis.

U2 - 10.1002/chem.201704149

DO - 10.1002/chem.201704149

M3 - Literature review

VL - 24

SP - 3101

EP - 3112

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 13

ER -