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Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Complete stereocontrol in the synthesis of macrocyclic lanthanide complexes
T2 - direct formation of enantiopure systems for circularly polarised luminescence applications
AU - Evans, Nicholas H.
AU - Carr, Rachel
AU - Delbianco, Martina
AU - Pal, Robert
AU - Yufit, Dmitry S.
AU - Parker, David
PY - 2013/11/28
Y1 - 2013/11/28
N2 - Mono-C-substitution of the 1,4,7-triazacyclononane ring induces formation of single enantiomers of Eu(III) complexes with nonadentate N6O3 ligands. The absolute configuration of each complex is determined by the stereogenicity of the C-substituent, revealed by comparison of the sign and sequence of CPL transitions for a series of complexes.
AB - Mono-C-substitution of the 1,4,7-triazacyclononane ring induces formation of single enantiomers of Eu(III) complexes with nonadentate N6O3 ligands. The absolute configuration of each complex is determined by the stereogenicity of the C-substituent, revealed by comparison of the sign and sequence of CPL transitions for a series of complexes.
U2 - 10.1039/C3DT52425F
DO - 10.1039/C3DT52425F
M3 - Journal article
VL - 42
SP - 15610
EP - 15616
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
IS - 44
ER -