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Cyclic diperoxides as sources of radicals for the initiation of the radical polymerisation of methyl methacrylate.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Cyclic diperoxides as sources of radicals for the initiation of the radical polymerisation of methyl methacrylate. / Lockley, J. E.; Ebdon, J. R.; Rimmer, S. et al.
In: Macromolecular Rapid Communications, Vol. 21, No. 12, 08.2000, p. 841-845.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Lockley, JE, Ebdon, JR, Rimmer, S & Tabner, BJ 2000, 'Cyclic diperoxides as sources of radicals for the initiation of the radical polymerisation of methyl methacrylate.', Macromolecular Rapid Communications, vol. 21, no. 12, pp. 841-845. https://doi.org/10.1002/1521-3927(20000801)21:12<841::AID-MARC841>3.0.CO;2-Y

APA

Lockley, J. E., Ebdon, J. R., Rimmer, S., & Tabner, B. J. (2000). Cyclic diperoxides as sources of radicals for the initiation of the radical polymerisation of methyl methacrylate. Macromolecular Rapid Communications, 21(12), 841-845. https://doi.org/10.1002/1521-3927(20000801)21:12<841::AID-MARC841>3.0.CO;2-Y

Vancouver

Lockley JE, Ebdon JR, Rimmer S, Tabner BJ. Cyclic diperoxides as sources of radicals for the initiation of the radical polymerisation of methyl methacrylate. Macromolecular Rapid Communications. 2000 Aug;21(12):841-845. doi: 10.1002/1521-3927(20000801)21:12<841::AID-MARC841>3.0.CO;2-Y

Author

Lockley, J. E. ; Ebdon, J. R. ; Rimmer, S. et al. / Cyclic diperoxides as sources of radicals for the initiation of the radical polymerisation of methyl methacrylate. In: Macromolecular Rapid Communications. 2000 ; Vol. 21, No. 12. pp. 841-845.

Bibtex

@article{6c6a5c8cfc9f4ebdb6a498e6062ca0d1,
title = "Cyclic diperoxides as sources of radicals for the initiation of the radical polymerisation of methyl methacrylate.",
abstract = "Thermolysis of cyclic diperoxides gave radicals. When solution polymerization of MMA was initiated by acetone cyclic diperoxide transfer to solvent was the dominant feature of the initiation process. However, transfer in the bulk polymerization of MMA was not a significant feature. Initiation of polymerization of MMA in solution by dibenzyl ketone cyclic diperoxide occurred at lower temperatures, and also aromatic end groups, derived from initiation by benzyl radicals, could be detected by 1H NMR.",
author = "Lockley, {J. E.} and Ebdon, {J. R.} and S. Rimmer and Tabner, {Brian J.}",
year = "2000",
month = aug,
doi = "10.1002/1521-3927(20000801)21:12<841::AID-MARC841>3.0.CO;2-Y",
language = "English",
volume = "21",
pages = "841--845",
journal = "Macromolecular Rapid Communications",
issn = "1022-1336",
publisher = "Wiley-VCH Verlag",
number = "12",

}

RIS

TY - JOUR

T1 - Cyclic diperoxides as sources of radicals for the initiation of the radical polymerisation of methyl methacrylate.

AU - Lockley, J. E.

AU - Ebdon, J. R.

AU - Rimmer, S.

AU - Tabner, Brian J.

PY - 2000/8

Y1 - 2000/8

N2 - Thermolysis of cyclic diperoxides gave radicals. When solution polymerization of MMA was initiated by acetone cyclic diperoxide transfer to solvent was the dominant feature of the initiation process. However, transfer in the bulk polymerization of MMA was not a significant feature. Initiation of polymerization of MMA in solution by dibenzyl ketone cyclic diperoxide occurred at lower temperatures, and also aromatic end groups, derived from initiation by benzyl radicals, could be detected by 1H NMR.

AB - Thermolysis of cyclic diperoxides gave radicals. When solution polymerization of MMA was initiated by acetone cyclic diperoxide transfer to solvent was the dominant feature of the initiation process. However, transfer in the bulk polymerization of MMA was not a significant feature. Initiation of polymerization of MMA in solution by dibenzyl ketone cyclic diperoxide occurred at lower temperatures, and also aromatic end groups, derived from initiation by benzyl radicals, could be detected by 1H NMR.

U2 - 10.1002/1521-3927(20000801)21:12<841::AID-MARC841>3.0.CO;2-Y

DO - 10.1002/1521-3927(20000801)21:12<841::AID-MARC841>3.0.CO;2-Y

M3 - Journal article

VL - 21

SP - 841

EP - 845

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

SN - 1022-1336

IS - 12

ER -