Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Depositional time trends and remobilisation of PCBs in lake sediments.
AU - Gevao, Bondi
AU - Hamilton-Taylor, John
AU - Murdoch, Chris
AU - Jones, Kevin C.
AU - Kelly, Mike
AU - Tabner, Brian J.
PY - 1997/11
Y1 - 1997/11
N2 - The vertical distribution of PCBs was measured in a dated core from the profundal sediments of Esthwaite Water, U.K. The resulting historical record of ∑PCB deposition agreed well with published U.K. production data. Ratios between the various PCB homolog groups revealed significant compositional variations with depth. Sediments deposited in the last 10 years and sediments deposited before PCB production began are both relatively enriched in the less chlorinated homolog groups. When considered with other available data, these enrichments provide evidence for post-depositional mobility of PCBs favoring the more aqueous soluble and volatile compounds. The results lend further support to a growing body of evidence that recyling of PCBs is occurring between the sediments and overlying waters, associated with solubilization and diffusive transport.
AB - The vertical distribution of PCBs was measured in a dated core from the profundal sediments of Esthwaite Water, U.K. The resulting historical record of ∑PCB deposition agreed well with published U.K. production data. Ratios between the various PCB homolog groups revealed significant compositional variations with depth. Sediments deposited in the last 10 years and sediments deposited before PCB production began are both relatively enriched in the less chlorinated homolog groups. When considered with other available data, these enrichments provide evidence for post-depositional mobility of PCBs favoring the more aqueous soluble and volatile compounds. The results lend further support to a growing body of evidence that recyling of PCBs is occurring between the sediments and overlying waters, associated with solubilization and diffusive transport.
U2 - 10.1021/es970276f
DO - 10.1021/es970276f
M3 - Journal article
VL - 31
SP - 3274
EP - 3280
JO - Environmental Science and Technology
JF - Environmental Science and Technology
SN - 0013-936X
IS - 11
ER -