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Detecting phase transitions in supercritical mixtures: an enabling tool for greener chemical reactions

Research output: Contribution to journalLiterature review

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Detecting phase transitions in supercritical mixtures : an enabling tool for greener chemical reactions. / Ke, Jie; Sanchez-Vicente, Yolanda; Akien, Geoffrey R.; Novitskiy, Alexander A.; Comak, Gurbuz; Bagratashvili, Victor N.; George, Michael W.; Poliakoff, Martyn.

In: Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 466, No. 2122, 08.10.2010, p. 2799-2818.

Research output: Contribution to journalLiterature review

Harvard

Ke, J, Sanchez-Vicente, Y, Akien, GR, Novitskiy, AA, Comak, G, Bagratashvili, VN, George, MW & Poliakoff, M 2010, 'Detecting phase transitions in supercritical mixtures: an enabling tool for greener chemical reactions', Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, vol. 466, no. 2122, pp. 2799-2818. https://doi.org/10.1098/rspa.2010.0267

APA

Ke, J., Sanchez-Vicente, Y., Akien, G. R., Novitskiy, A. A., Comak, G., Bagratashvili, V. N., George, M. W., & Poliakoff, M. (2010). Detecting phase transitions in supercritical mixtures: an enabling tool for greener chemical reactions. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, 466(2122), 2799-2818. https://doi.org/10.1098/rspa.2010.0267

Vancouver

Ke J, Sanchez-Vicente Y, Akien GR, Novitskiy AA, Comak G, Bagratashvili VN et al. Detecting phase transitions in supercritical mixtures: an enabling tool for greener chemical reactions. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences. 2010 Oct 8;466(2122):2799-2818. https://doi.org/10.1098/rspa.2010.0267

Author

Ke, Jie ; Sanchez-Vicente, Yolanda ; Akien, Geoffrey R. ; Novitskiy, Alexander A. ; Comak, Gurbuz ; Bagratashvili, Victor N. ; George, Michael W. ; Poliakoff, Martyn. / Detecting phase transitions in supercritical mixtures : an enabling tool for greener chemical reactions. In: Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences. 2010 ; Vol. 466, No. 2122. pp. 2799-2818.

Bibtex

@article{b8076e2bb9b74011bd07c154ecfce32d,
title = "Detecting phase transitions in supercritical mixtures: an enabling tool for greener chemical reactions",
abstract = "Detecting phase transitions in high-pressure CO(2) and supercritical fluids was first attempted in the nineteenth century. By contrast, Green Chemistry, the design and implementation of cleaner methods of manufacturing and processing chemicals, is barely 20 years old. Now, the use of CO(2) as an environmentally more acceptable replacement for traditional solvents for greener chemical reactions is creating the need for new, more rapid methods for elucidating high-pressure phase behaviour. This paper describes the advantages and limitations of a number of approaches, developed in Nottingham, to meet this need, including acoustic measurements, shear-mode quartz sensors, the fibre-optic reflectometer, the use of holey fibres, attenuated total reflectance infrared spectroscopy and pressure drop measurements.",
keywords = "phase equilibrium, sensors, supercritical fluids, Green Chemistry, high pressure, critical points, MODE PIEZOELECTRIC SENSOR, CRITICAL-POINT CHANGE, CARBON-DIOXIDE, ACOUSTIC DETERMINATION, FLUID MIXTURES, HIGH-PRESSURES, CO2, EQUILIBRIA, HYDROFORMYLATION, TEMPERATURES",
author = "Jie Ke and Yolanda Sanchez-Vicente and Akien, {Geoffrey R.} and Novitskiy, {Alexander A.} and Gurbuz Comak and Bagratashvili, {Victor N.} and George, {Michael W.} and Martyn Poliakoff",
year = "2010",
month = oct
day = "8",
doi = "10.1098/rspa.2010.0267",
language = "English",
volume = "466",
pages = "2799--2818",
journal = "Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences",
issn = "1364-5021",
publisher = "Royal Society of Chemistry Publishing",
number = "2122",

}

RIS

TY - JOUR

T1 - Detecting phase transitions in supercritical mixtures

T2 - an enabling tool for greener chemical reactions

AU - Ke, Jie

AU - Sanchez-Vicente, Yolanda

AU - Akien, Geoffrey R.

AU - Novitskiy, Alexander A.

AU - Comak, Gurbuz

AU - Bagratashvili, Victor N.

AU - George, Michael W.

AU - Poliakoff, Martyn

PY - 2010/10/8

Y1 - 2010/10/8

N2 - Detecting phase transitions in high-pressure CO(2) and supercritical fluids was first attempted in the nineteenth century. By contrast, Green Chemistry, the design and implementation of cleaner methods of manufacturing and processing chemicals, is barely 20 years old. Now, the use of CO(2) as an environmentally more acceptable replacement for traditional solvents for greener chemical reactions is creating the need for new, more rapid methods for elucidating high-pressure phase behaviour. This paper describes the advantages and limitations of a number of approaches, developed in Nottingham, to meet this need, including acoustic measurements, shear-mode quartz sensors, the fibre-optic reflectometer, the use of holey fibres, attenuated total reflectance infrared spectroscopy and pressure drop measurements.

AB - Detecting phase transitions in high-pressure CO(2) and supercritical fluids was first attempted in the nineteenth century. By contrast, Green Chemistry, the design and implementation of cleaner methods of manufacturing and processing chemicals, is barely 20 years old. Now, the use of CO(2) as an environmentally more acceptable replacement for traditional solvents for greener chemical reactions is creating the need for new, more rapid methods for elucidating high-pressure phase behaviour. This paper describes the advantages and limitations of a number of approaches, developed in Nottingham, to meet this need, including acoustic measurements, shear-mode quartz sensors, the fibre-optic reflectometer, the use of holey fibres, attenuated total reflectance infrared spectroscopy and pressure drop measurements.

KW - phase equilibrium

KW - sensors

KW - supercritical fluids

KW - Green Chemistry

KW - high pressure

KW - critical points

KW - MODE PIEZOELECTRIC SENSOR

KW - CRITICAL-POINT CHANGE

KW - CARBON-DIOXIDE

KW - ACOUSTIC DETERMINATION

KW - FLUID MIXTURES

KW - HIGH-PRESSURES

KW - CO2

KW - EQUILIBRIA

KW - HYDROFORMYLATION

KW - TEMPERATURES

U2 - 10.1098/rspa.2010.0267

DO - 10.1098/rspa.2010.0267

M3 - Literature review

VL - 466

SP - 2799

EP - 2818

JO - Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences

JF - Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences

SN - 1364-5021

IS - 2122

ER -