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Exploring molecular recognition pathways within a family of gelators with different hydrogen bonding motifs

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Exploring molecular recognition pathways within a family of gelators with different hydrogen bonding motifs. / Hardy, John G.; Hirst, Andrew R.; Ashworth, Ian et al.
In: Tetrahedron, Vol. 63, No. 31, 30.07.2007, p. 7397-7406.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

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Hardy JG, Hirst AR, Ashworth I, Brennan C, Smith DK. Exploring molecular recognition pathways within a family of gelators with different hydrogen bonding motifs. Tetrahedron. 2007 Jul 30;63(31):7397-7406. doi: 10.1016/j.tet.2007.03.120

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Hardy, John G. ; Hirst, Andrew R. ; Ashworth, Ian et al. / Exploring molecular recognition pathways within a family of gelators with different hydrogen bonding motifs. In: Tetrahedron. 2007 ; Vol. 63, No. 31. pp. 7397-7406.

Bibtex

@article{a953d92f10204f0f8ef1761868ab4350,
title = "Exploring molecular recognition pathways within a family of gelators with different hydrogen bonding motifs",
abstract = "We report the synthesis of a family of gelators in which alkyl chains are connected to the amino groups of L-lysine methyl ester using a range of different hydrogen bonding linking groups (carbamate, amide, urea, thiourea and diacylhydrazine) using simple synthetic methodology based on isocyanate or acid chloride chemistry. The ability of these compounds to gelate organic solvents such as toluene or cyclohexane can be directly related to the ability of the linking group to form intermolecular hydrogen bonds. In general terms, the ability to structure solvents can be considered as: thiourea ",
keywords = "GEL-PHASE MATERIALS, 2-COMPONENT DENDRITIC GEL, L-LYSINE DERIVATIVES, WEIGHT HYDROGELATORS, ORGANIC LIQUIDS, CONTROLLABLE NANOMATERIALS, SUPRAMOLECULAR GELS, PEPTIDIC DENDRIMERS, MASS GELATORS, ONE-COMPONENT, Chemistry(all), Materials Science (miscellaneous)",
author = "Hardy, {John G.} and Hirst, {Andrew R.} and Ian Ashworth and Colin Brennan and Smith, {David K.}",
year = "2007",
month = jul,
day = "30",
doi = "10.1016/j.tet.2007.03.120",
language = "English",
volume = "63",
pages = "7397--7406",
journal = "Tetrahedron",
issn = "0040-4020",
publisher = "Elsevier Limited",
number = "31",

}

RIS

TY - JOUR

T1 - Exploring molecular recognition pathways within a family of gelators with different hydrogen bonding motifs

AU - Hardy, John G.

AU - Hirst, Andrew R.

AU - Ashworth, Ian

AU - Brennan, Colin

AU - Smith, David K.

PY - 2007/7/30

Y1 - 2007/7/30

N2 - We report the synthesis of a family of gelators in which alkyl chains are connected to the amino groups of L-lysine methyl ester using a range of different hydrogen bonding linking groups (carbamate, amide, urea, thiourea and diacylhydrazine) using simple synthetic methodology based on isocyanate or acid chloride chemistry. The ability of these compounds to gelate organic solvents such as toluene or cyclohexane can be directly related to the ability of the linking group to form intermolecular hydrogen bonds. In general terms, the ability to structure solvents can be considered as: thiourea

AB - We report the synthesis of a family of gelators in which alkyl chains are connected to the amino groups of L-lysine methyl ester using a range of different hydrogen bonding linking groups (carbamate, amide, urea, thiourea and diacylhydrazine) using simple synthetic methodology based on isocyanate or acid chloride chemistry. The ability of these compounds to gelate organic solvents such as toluene or cyclohexane can be directly related to the ability of the linking group to form intermolecular hydrogen bonds. In general terms, the ability to structure solvents can be considered as: thiourea

KW - GEL-PHASE MATERIALS

KW - 2-COMPONENT DENDRITIC GEL

KW - L-LYSINE DERIVATIVES

KW - WEIGHT HYDROGELATORS

KW - ORGANIC LIQUIDS

KW - CONTROLLABLE NANOMATERIALS

KW - SUPRAMOLECULAR GELS

KW - PEPTIDIC DENDRIMERS

KW - MASS GELATORS

KW - ONE-COMPONENT

KW - Chemistry(all)

KW - Materials Science (miscellaneous)

U2 - 10.1016/j.tet.2007.03.120

DO - 10.1016/j.tet.2007.03.120

M3 - Journal article

VL - 63

SP - 7397

EP - 7406

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

IS - 31

ER -