Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Field derived accumulation and release kinetics of DDTs in plants.
AU - Di Guardo, Antonio
AU - Nizzetto, Luca
AU - Infantino, Alfonso
AU - Colombo, Ilaria
AU - Saporiti, Elena
AU - Jones, Kevin C.
PY - 2008/8
Y1 - 2008/8
N2 - Vegetation plays an important role in influencing the air/surface exchange of semivolatile organic compounds (SOCs). In order to predict the capability of different plant species to capture chemicals from the air, plant–air partition coefficients and kinetic accumulation parameters must be defined. In this study, potted plants of three different species were transferred to the vicinity of a source point for DDT, namely a contaminated area around a former production plant in Italy. Leaves were constantly sampled in order to follow the uptake from air over time. Later, the potted plants were transported to a location characterized by background diffuse air concentrations for the release phase. Coupling the experimental results with a two-compartment accumulation model it was possible to derive the kinetics parameters and the plant–air partition coefficient KPA for p,p′-DDT. The log KPA (on a mass/volume basis) ranged between 1.7 and 2.2 for the different species. The uncertainties related to the different phenomena involved in a field uptake/release experiment are discussed.
AB - Vegetation plays an important role in influencing the air/surface exchange of semivolatile organic compounds (SOCs). In order to predict the capability of different plant species to capture chemicals from the air, plant–air partition coefficients and kinetic accumulation parameters must be defined. In this study, potted plants of three different species were transferred to the vicinity of a source point for DDT, namely a contaminated area around a former production plant in Italy. Leaves were constantly sampled in order to follow the uptake from air over time. Later, the potted plants were transported to a location characterized by background diffuse air concentrations for the release phase. Coupling the experimental results with a two-compartment accumulation model it was possible to derive the kinetics parameters and the plant–air partition coefficient KPA for p,p′-DDT. The log KPA (on a mass/volume basis) ranged between 1.7 and 2.2 for the different species. The uncertainties related to the different phenomena involved in a field uptake/release experiment are discussed.
KW - Persistent organic pollutants
KW - Mass transfer coefficient
KW - Bioaccumulation factor
KW - Vegetation
KW - Oak
KW - Cherry laurel
KW - Azalea
U2 - 10.1016/j.chemosphere.2008.04.072
DO - 10.1016/j.chemosphere.2008.04.072
M3 - Journal article
VL - 72
SP - 1497
EP - 1503
JO - Chemosphere
JF - Chemosphere
SN - 0045-6535
IS - 10
ER -