Functionalisation of terpyridine complexes containing the [Re(CO)3Cl]+ moiety

Chemistry

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https://doi.org/10.1039/c0dt00174k
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Functionalisation of terpyridine complexes containing the [Re(CO)3Cl]+ moiety. / Amoroso, Angelo J. ; Banu, Afrosa; Coogan, Michael et al.
In: Dalton Transactions, Vol. 39, No. 30, 2010, p. 6993-7003.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Amoroso, AJ, Banu, A, Coogan, M, Edwards, PG, Hossain, G & Abdul Malik, KM 2010, 'Functionalisation of terpyridine complexes containing the [Re(CO)3Cl]+ moiety', Dalton Transactions, vol. 39, no. 30, pp. 6993-7003. https://doi.org/10.1039/c0dt00174k

APA

Amoroso, A. J., Banu, A., Coogan, M., Edwards, P. G., Hossain, G., & Abdul Malik, K. M. (2010). Functionalisation of terpyridine complexes containing the [Re(CO)3Cl]+ moiety. Dalton Transactions, 39(30), 6993-7003. https://doi.org/10.1039/c0dt00174k

Vancouver

Amoroso AJ, Banu A, Coogan M, Edwards PG, Hossain G, Abdul Malik KM. Functionalisation of terpyridine complexes containing the [Re(CO)3Cl]+ moiety. Dalton Transactions. 2010;39(30):6993-7003. doi: 10.1039/c0dt00174k

Author

Amoroso, Angelo J. ; Banu, Afrosa ; Coogan, Michael et al. / Functionalisation of terpyridine complexes containing the [Re(CO)3Cl]+ moiety. In: Dalton Transactions. 2010 ; Vol. 39, No. 30. pp. 6993-7003.

Bibtex

@article{7d9e2d675e274b8190acea58c6ba9497,

title = "Functionalisation of terpyridine complexes containing the [Re(CO)3Cl]+ moiety",

abstract = "The investigation into the substitution and addition chemistry of Re(σ2-terpy)(CO)3Cl shows that the chloride in Re(σ2-terpy)(CO)3Cl (1) may be substituted for acetonitrile to give [Re(σ2-terpy)(CO)3(CH3CN)][PF6] (2), but in the cationic complex [Re(σ2-terpyMe)(CO)3Cl][PF6] (4), where the pendant pyridine has been methylated, substitution of the chloride could not be achieved using standard conditions. However, use of [Re(σ2-terpyMe)(CO)3I][PF6] (3) results in the formation of [Re(σ2-terpyMe)(CO)3(CH3CN)][PF6]2 (5). The acetonitrile ligand in complex 2 was found to be labile and could be substituted by pyridine donors.",

author = "Amoroso, {Angelo J.} and Afrosa Banu and Michael Coogan and Edwards, {Peter G.} and Golzar Hossain and {Abdul Malik}, {K. M.}",

year = "2010",

doi = "10.1039/c0dt00174k",

language = "English",

volume = "39",

pages = "6993--7003",

journal = "Dalton Transactions",

issn = "1477-9234",

publisher = "Royal Society of Chemistry",

number = "30",

}

RIS

TY - JOUR

T1 - Functionalisation of terpyridine complexes containing the [Re(CO)3Cl]+ moiety

AU - Amoroso, Angelo J.

AU - Banu, Afrosa

AU - Coogan, Michael

AU - Edwards, Peter G.

AU - Hossain, Golzar

AU - Abdul Malik, K. M.

PY - 2010

Y1 - 2010

N2 - The investigation into the substitution and addition chemistry of Re(σ2-terpy)(CO)3Cl shows that the chloride in Re(σ2-terpy)(CO)3Cl (1) may be substituted for acetonitrile to give [Re(σ2-terpy)(CO)3(CH3CN)][PF6] (2), but in the cationic complex [Re(σ2-terpyMe)(CO)3Cl][PF6] (4), where the pendant pyridine has been methylated, substitution of the chloride could not be achieved using standard conditions. However, use of [Re(σ2-terpyMe)(CO)3I][PF6] (3) results in the formation of [Re(σ2-terpyMe)(CO)3(CH3CN)][PF6]2 (5). The acetonitrile ligand in complex 2 was found to be labile and could be substituted by pyridine donors.

AB - The investigation into the substitution and addition chemistry of Re(σ2-terpy)(CO)3Cl shows that the chloride in Re(σ2-terpy)(CO)3Cl (1) may be substituted for acetonitrile to give [Re(σ2-terpy)(CO)3(CH3CN)][PF6] (2), but in the cationic complex [Re(σ2-terpyMe)(CO)3Cl][PF6] (4), where the pendant pyridine has been methylated, substitution of the chloride could not be achieved using standard conditions. However, use of [Re(σ2-terpyMe)(CO)3I][PF6] (3) results in the formation of [Re(σ2-terpyMe)(CO)3(CH3CN)][PF6]2 (5). The acetonitrile ligand in complex 2 was found to be labile and could be substituted by pyridine donors.

U2 - 10.1039/c0dt00174k

DO - 10.1039/c0dt00174k

M3 - Journal article

VL - 39

SP - 6993

EP - 7003

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9234

IS - 30

ER -

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