Home > Research > Publications & Outputs > Heteronuclear 3 d/DyIII coordination clusters a...

Links

Text available via DOI:

View graph of relations

Heteronuclear 3 d/DyIII coordination clusters as catalysts in a domino reaction

Research output: Contribution to Journal/MagazineJournal articlepeer-review

Published
  • Kieran Griffiths
  • Christopher W.D. Gallop
  • Alaa Abdul-Sada
  • Alfredo Vargas
  • Oscar Navarro
  • George E. Kostakis
Close
<mark>Journal publication date</mark>20/04/2015
<mark>Journal</mark>Chemistry - A European Journal
Issue number17
Volume21
Number of pages4
Pages (from-to)6358-6361
Publication StatusPublished
<mark>Original language</mark>English

Abstract

Three isoskeletal tetranuclear coordination clusters with general formula [MII2DyIII2L4(EtOH)6](ClO4)2·2 EtOH, (M=Co, 1; M=Ni, 2) and [NiII2DyIII2L4Cl2(CH3CN)2]·2 CH3CN (3), have been synthesized and characterized. These air-stable compounds, and in particular 3, display efficient homogeneous catalytic behavior in the room-temperature synthesis of trans-4,5-diaminocyclopent-2-enones from 2-furaldehyde and primary or secondary amines under a non-inert atmosphere.