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Hydrogenation of CO(2)-Expanded Liquid Terpenes: Phase Equilibrium-Controlled Kinetics

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Publication date2009
Host publicationGas-expanded liquids and near-critcial media : green chemistry and engineering
EditorsKeith W. Hutchenson, Aaron M. Scurto, Bala Subramaniam
Place of PublicationWashington, D.C.
PublisherAmerican Chemical Society
Pages191-201
Number of pages11
ISBN (Print)978-0-8412-6971-2
<mark>Original language</mark>English
EventSymposium on Green Chemistry and Engineering with Gas-Expanded Liquids and Near-Critical Media - Boston, Morocco

Conference

ConferenceSymposium on Green Chemistry and Engineering with Gas-Expanded Liquids and Near-Critical Media
CountryMorocco
CityBoston
Period19/08/0723/08/07

Publication series

NameACS Symposium Series
PublisherAmerican Chemical Society
Volume1006
ISSN (Print)0097-6156

Conference

ConferenceSymposium on Green Chemistry and Engineering with Gas-Expanded Liquids and Near-Critical Media
CountryMorocco
CityBoston
Period19/08/0723/08/07

Abstract

The hydrogenation of two liquid terpenes, alpha-pinene and limonene, was carried out in the presence of high-pressure carbon dioxide, using carbon-supported Pt catalysts. Phase equilibrium data on terpene + CO(2) + hydrogen were used to interpret the kinetics of hydrogenation in liquid + vapor systems close to the critical lines of the mixtures.