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Influence of UV-B radiation and temperature on photodegradation of PAHs : preliminary results.

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Influence of UV-B radiation and temperature on photodegradation of PAHs : preliminary results. / Nadal, Martí; Wargent, Jason J.; Jones, Kevin C. et al.
In: Journal of Atmospheric Chemistry, Vol. 55, No. 3, 11.2006, p. 241-252.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

Harvard

Nadal, M, Wargent, JJ, Jones, KC, Paul, ND, Schuhmacher, M & Domingo, JL 2006, 'Influence of UV-B radiation and temperature on photodegradation of PAHs : preliminary results.', Journal of Atmospheric Chemistry, vol. 55, no. 3, pp. 241-252. https://doi.org/10.1007/s10874-006-9037-7

APA

Nadal, M., Wargent, J. J., Jones, K. C., Paul, N. D., Schuhmacher, M., & Domingo, J. L. (2006). Influence of UV-B radiation and temperature on photodegradation of PAHs : preliminary results. Journal of Atmospheric Chemistry, 55(3), 241-252. https://doi.org/10.1007/s10874-006-9037-7

Vancouver

Nadal M, Wargent JJ, Jones KC, Paul ND, Schuhmacher M, Domingo JL. Influence of UV-B radiation and temperature on photodegradation of PAHs : preliminary results. Journal of Atmospheric Chemistry. 2006 Nov;55(3):241-252. doi: 10.1007/s10874-006-9037-7

Author

Nadal, Martí ; Wargent, Jason J. ; Jones, Kevin C. et al. / Influence of UV-B radiation and temperature on photodegradation of PAHs : preliminary results. In: Journal of Atmospheric Chemistry. 2006 ; Vol. 55, No. 3. pp. 241-252.

Bibtex

@article{e83ac7549f0844a797dbfaa6d7643659,
title = "Influence of UV-B radiation and temperature on photodegradation of PAHs : preliminary results.",
abstract = "The joint impact of UV-B radiation and temperature on photodegradation of polycyclic aromatic hydrocarbons (PAHs) sorbed to an organic solvent was assessed in this study. This approach was experimentally performed in a laboratory investigation by means of comparison of two different environments: Atlantic (Lancaster, UK) and Mediterranean (Tarragona, Catalonia, Spain) climatic conditions. The concentration of 10 PAHs contained in a tetradecane solution was compared under two different temperatures (10 and 20°C) and UV-B doses (6.5 and 22.5 kJ m−2 day−1). No photodegradation was observed for the heaviest hydrocarbons (benzo(a)anthracene, chrysene, benzo(a)pyrene, dibenzo(g,h,i)perylene and coronene). In general terms, the half-life of PAHs was highly dependent on their molecular weight. Significant faster photodegradation rates were detected specially for light PAHs. It indicates that a synergistic effect occurred when both temperature and UV-B dose increased. This synergism might have a great implication on the long-range transport of environmental organic pollutants taking into account that low-latitude areas are the hottest and most irradiated of the planet.",
keywords = "polycyclic aromatic hydrocarbons - environmental conditions - photodegradation - tetradecane - UV-B radiation - temperature",
author = "Mart{\'i} Nadal and Wargent, {Jason J.} and Jones, {Kevin C.} and Paul, {Nigel D.} and Marta Schuhmacher and Domingo, {Jos{\'e} L.}",
year = "2006",
month = nov,
doi = "10.1007/s10874-006-9037-7",
language = "English",
volume = "55",
pages = "241--252",
journal = "Journal of Atmospheric Chemistry",
issn = "0167-7764",
publisher = "Springer Netherlands",
number = "3",

}

RIS

TY - JOUR

T1 - Influence of UV-B radiation and temperature on photodegradation of PAHs : preliminary results.

AU - Nadal, Martí

AU - Wargent, Jason J.

AU - Jones, Kevin C.

AU - Paul, Nigel D.

AU - Schuhmacher, Marta

AU - Domingo, José L.

PY - 2006/11

Y1 - 2006/11

N2 - The joint impact of UV-B radiation and temperature on photodegradation of polycyclic aromatic hydrocarbons (PAHs) sorbed to an organic solvent was assessed in this study. This approach was experimentally performed in a laboratory investigation by means of comparison of two different environments: Atlantic (Lancaster, UK) and Mediterranean (Tarragona, Catalonia, Spain) climatic conditions. The concentration of 10 PAHs contained in a tetradecane solution was compared under two different temperatures (10 and 20°C) and UV-B doses (6.5 and 22.5 kJ m−2 day−1). No photodegradation was observed for the heaviest hydrocarbons (benzo(a)anthracene, chrysene, benzo(a)pyrene, dibenzo(g,h,i)perylene and coronene). In general terms, the half-life of PAHs was highly dependent on their molecular weight. Significant faster photodegradation rates were detected specially for light PAHs. It indicates that a synergistic effect occurred when both temperature and UV-B dose increased. This synergism might have a great implication on the long-range transport of environmental organic pollutants taking into account that low-latitude areas are the hottest and most irradiated of the planet.

AB - The joint impact of UV-B radiation and temperature on photodegradation of polycyclic aromatic hydrocarbons (PAHs) sorbed to an organic solvent was assessed in this study. This approach was experimentally performed in a laboratory investigation by means of comparison of two different environments: Atlantic (Lancaster, UK) and Mediterranean (Tarragona, Catalonia, Spain) climatic conditions. The concentration of 10 PAHs contained in a tetradecane solution was compared under two different temperatures (10 and 20°C) and UV-B doses (6.5 and 22.5 kJ m−2 day−1). No photodegradation was observed for the heaviest hydrocarbons (benzo(a)anthracene, chrysene, benzo(a)pyrene, dibenzo(g,h,i)perylene and coronene). In general terms, the half-life of PAHs was highly dependent on their molecular weight. Significant faster photodegradation rates were detected specially for light PAHs. It indicates that a synergistic effect occurred when both temperature and UV-B dose increased. This synergism might have a great implication on the long-range transport of environmental organic pollutants taking into account that low-latitude areas are the hottest and most irradiated of the planet.

KW - polycyclic aromatic hydrocarbons - environmental conditions - photodegradation - tetradecane - UV-B radiation - temperature

U2 - 10.1007/s10874-006-9037-7

DO - 10.1007/s10874-006-9037-7

M3 - Journal article

VL - 55

SP - 241

EP - 252

JO - Journal of Atmospheric Chemistry

JF - Journal of Atmospheric Chemistry

SN - 0167-7764

IS - 3

ER -