Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Influence of UV-B radiation and temperature on photodegradation of PAHs : preliminary results.
AU - Nadal, Martí
AU - Wargent, Jason J.
AU - Jones, Kevin C.
AU - Paul, Nigel D.
AU - Schuhmacher, Marta
AU - Domingo, José L.
PY - 2006/11
Y1 - 2006/11
N2 - The joint impact of UV-B radiation and temperature on photodegradation of polycyclic aromatic hydrocarbons (PAHs) sorbed to an organic solvent was assessed in this study. This approach was experimentally performed in a laboratory investigation by means of comparison of two different environments: Atlantic (Lancaster, UK) and Mediterranean (Tarragona, Catalonia, Spain) climatic conditions. The concentration of 10 PAHs contained in a tetradecane solution was compared under two different temperatures (10 and 20°C) and UV-B doses (6.5 and 22.5 kJ m−2 day−1). No photodegradation was observed for the heaviest hydrocarbons (benzo(a)anthracene, chrysene, benzo(a)pyrene, dibenzo(g,h,i)perylene and coronene). In general terms, the half-life of PAHs was highly dependent on their molecular weight. Significant faster photodegradation rates were detected specially for light PAHs. It indicates that a synergistic effect occurred when both temperature and UV-B dose increased. This synergism might have a great implication on the long-range transport of environmental organic pollutants taking into account that low-latitude areas are the hottest and most irradiated of the planet.
AB - The joint impact of UV-B radiation and temperature on photodegradation of polycyclic aromatic hydrocarbons (PAHs) sorbed to an organic solvent was assessed in this study. This approach was experimentally performed in a laboratory investigation by means of comparison of two different environments: Atlantic (Lancaster, UK) and Mediterranean (Tarragona, Catalonia, Spain) climatic conditions. The concentration of 10 PAHs contained in a tetradecane solution was compared under two different temperatures (10 and 20°C) and UV-B doses (6.5 and 22.5 kJ m−2 day−1). No photodegradation was observed for the heaviest hydrocarbons (benzo(a)anthracene, chrysene, benzo(a)pyrene, dibenzo(g,h,i)perylene and coronene). In general terms, the half-life of PAHs was highly dependent on their molecular weight. Significant faster photodegradation rates were detected specially for light PAHs. It indicates that a synergistic effect occurred when both temperature and UV-B dose increased. This synergism might have a great implication on the long-range transport of environmental organic pollutants taking into account that low-latitude areas are the hottest and most irradiated of the planet.
KW - polycyclic aromatic hydrocarbons - environmental conditions - photodegradation - tetradecane - UV-B radiation - temperature
U2 - 10.1007/s10874-006-9037-7
DO - 10.1007/s10874-006-9037-7
M3 - Journal article
VL - 55
SP - 241
EP - 252
JO - Journal of Atmospheric Chemistry
JF - Journal of Atmospheric Chemistry
SN - 0167-7764
IS - 3
ER -