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Investigation of water adsorption on metal oxide surfaces under conditions representative of PuO2 storage containers

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Investigation of water adsorption on metal oxide surfaces under conditions representative of PuO2 storage containers. / Boxall, Colin; Murphy, Pat; Taylor, Robin et al.
In: ECS Transactions, Vol. 53, No. 21, 09.2013, p. 81-94.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Boxall, C, Murphy, P, Taylor, R & Woodhead, D 2013, 'Investigation of water adsorption on metal oxide surfaces under conditions representative of PuO2 storage containers', ECS Transactions, vol. 53, no. 21, pp. 81-94. https://doi.org/10.1149/05321.0081ecst

APA

Boxall, C., Murphy, P., Taylor, R., & Woodhead, D. (2013). Investigation of water adsorption on metal oxide surfaces under conditions representative of PuO2 storage containers. ECS Transactions, 53(21), 81-94. https://doi.org/10.1149/05321.0081ecst

Vancouver

Boxall C, Murphy P, Taylor R, Woodhead D. Investigation of water adsorption on metal oxide surfaces under conditions representative of PuO2 storage containers. ECS Transactions. 2013 Sept;53(21):81-94. doi: 10.1149/05321.0081ecst

Author

Boxall, Colin ; Murphy, Pat ; Taylor, Robin et al. / Investigation of water adsorption on metal oxide surfaces under conditions representative of PuO2 storage containers. In: ECS Transactions. 2013 ; Vol. 53, No. 21. pp. 81-94.

Bibtex

@article{96515bf786c64cb289cdf4942d97fb93,
title = "Investigation of water adsorption on metal oxide surfaces under conditions representative of PuO2 storage containers",
abstract = "We have developed a QCM (Quartz Crystal Microbalance) based method for direct gravimetric determination of water adsorption on PuO2 surrogate surfaces, especially CeO2, under conditions representative of those in a typical PuO2 storage can. In this application, the method of transduction of the QCM relies upon the linear relationship between the resonant frequency of piezoelectrically active quartz crystals and the mass adsorbed on the crystal surface. The effect of high temperature on the resonant frequency of coated QCM crystals has been compensated for by modeling the temperature dependence of the frequency response of the surrogate coated-QCM crystal in the absence of water.",
author = "Colin Boxall and Pat Murphy and Robin Taylor and Dave Woodhead",
year = "2013",
month = sep,
doi = "10.1149/05321.0081ecst",
language = "English",
volume = "53",
pages = "81--94",
journal = "ECS Transactions",
issn = "1938-6737",
publisher = "Electrochemical Society, Inc.",
number = "21",

}

RIS

TY - JOUR

T1 - Investigation of water adsorption on metal oxide surfaces under conditions representative of PuO2 storage containers

AU - Boxall, Colin

AU - Murphy, Pat

AU - Taylor, Robin

AU - Woodhead, Dave

PY - 2013/9

Y1 - 2013/9

N2 - We have developed a QCM (Quartz Crystal Microbalance) based method for direct gravimetric determination of water adsorption on PuO2 surrogate surfaces, especially CeO2, under conditions representative of those in a typical PuO2 storage can. In this application, the method of transduction of the QCM relies upon the linear relationship between the resonant frequency of piezoelectrically active quartz crystals and the mass adsorbed on the crystal surface. The effect of high temperature on the resonant frequency of coated QCM crystals has been compensated for by modeling the temperature dependence of the frequency response of the surrogate coated-QCM crystal in the absence of water.

AB - We have developed a QCM (Quartz Crystal Microbalance) based method for direct gravimetric determination of water adsorption on PuO2 surrogate surfaces, especially CeO2, under conditions representative of those in a typical PuO2 storage can. In this application, the method of transduction of the QCM relies upon the linear relationship between the resonant frequency of piezoelectrically active quartz crystals and the mass adsorbed on the crystal surface. The effect of high temperature on the resonant frequency of coated QCM crystals has been compensated for by modeling the temperature dependence of the frequency response of the surrogate coated-QCM crystal in the absence of water.

U2 - 10.1149/05321.0081ecst

DO - 10.1149/05321.0081ecst

M3 - Journal article

VL - 53

SP - 81

EP - 94

JO - ECS Transactions

JF - ECS Transactions

SN - 1938-6737

IS - 21

ER -