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Isoskeletal Schiff base polynuclear coordination clusters: Synthetic and theoretical aspects

Research output: Contribution to Journal/MagazineJournal articlepeer-review

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  • Kieran Griffiths
  • Vassiliki N. Dokorou
  • John Spencer
  • Alaa Abdul-Sada
  • Alfredo Vargas
  • George E. Kostakis
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<mark>Journal publication date</mark>1/01/2016
<mark>Journal</mark>CrystEngComm
Issue number5
Volume18
Number of pages10
Pages (from-to)704-713
Publication StatusPublished
<mark>Original language</mark>English

Abstract

This work addresses and enlightens synthetic aspects derived from our effort to systematically construct isoskeletal tetranuclear coordination clusters (CCs) of the general formula [TR2Ln2(LX)4(NO3)2(solv)2] possessing a specific defected dicubane topology, utilizing various substituted Schiff base organic ligands (H2LX) and NiII/CoII and Dy(OTf)3 salts. Our synthetic work is further supported by DFT studies.