Final published version
Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Metallophthalocyanin-ocenes
T2 - scandium phthalocyanines with an eta(5)-bound Cp ring
AU - Platel, Rachel H.
AU - Tasso, Thiago Teixeira
AU - Zhou, Wen
AU - Furuyama, Taniyuki
AU - Kobayashi, Nagao
AU - Leznoff, Daniel B.
PY - 2015/4/7
Y1 - 2015/4/7
N2 - A series of new scandium complexes supported by the phthalocyanine (Pc) ligand have been prepared and structurally characterized. Reaction of ScCl3 with phthalonitrile affords a mixture of PcScCl (1) and unreacted ScCl3, which upon addition of LiCH(SiMe3)(2) yields THF-soluble PcSc(mu-Cl-2) Li(THF)(2) (2). Metathesis with NaCp or LiCp* generates PcSc(eta(5)-C5H5) and PcSc(eta(5)-C5Me5), respectively, which represent the first examples of eta(5)-Cp metal phthalocyanines where the Cp fragment sandwiches the metal centre.
AB - A series of new scandium complexes supported by the phthalocyanine (Pc) ligand have been prepared and structurally characterized. Reaction of ScCl3 with phthalonitrile affords a mixture of PcScCl (1) and unreacted ScCl3, which upon addition of LiCH(SiMe3)(2) yields THF-soluble PcSc(mu-Cl-2) Li(THF)(2) (2). Metathesis with NaCp or LiCp* generates PcSc(eta(5)-C5H5) and PcSc(eta(5)-C5Me5), respectively, which represent the first examples of eta(5)-Cp metal phthalocyanines where the Cp fragment sandwiches the metal centre.
KW - PI-COMPLEXES
KW - DERIVATIVES
KW - ZIRCONIUM
KW - LIGANDS
U2 - 10.1039/c5cc00237k
DO - 10.1039/c5cc00237k
M3 - Journal article
VL - 51
SP - 5986
EP - 5989
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 27
ER -