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Microporous poly(tri(4-ethynylphenyl)amine) networks: synthesis, properties, and atomistic simulation

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Microporous poly(tri(4-ethynylphenyl)amine) networks: synthesis, properties, and atomistic simulation. / Jiang, Jia-Xing; Trewin, Abbie; Su, Fabing et al.
In: Macromolecules, Vol. 42, No. 7, 14.04.2009, p. 2658-2666.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Jiang, J-X, Trewin, A, Su, F, Wood, CD, Niu, H, Jones, JTA, Khimyak, YZ & Cooper, AI 2009, 'Microporous poly(tri(4-ethynylphenyl)amine) networks: synthesis, properties, and atomistic simulation', Macromolecules, vol. 42, no. 7, pp. 2658-2666. https://doi.org/10.1021/ma802625d

APA

Jiang, J-X., Trewin, A., Su, F., Wood, C. D., Niu, H., Jones, J. T. A., Khimyak, Y. Z., & Cooper, A. I. (2009). Microporous poly(tri(4-ethynylphenyl)amine) networks: synthesis, properties, and atomistic simulation. Macromolecules, 42(7), 2658-2666. https://doi.org/10.1021/ma802625d

Vancouver

Jiang J-X, Trewin A, Su F, Wood CD, Niu H, Jones JTA et al. Microporous poly(tri(4-ethynylphenyl)amine) networks: synthesis, properties, and atomistic simulation. Macromolecules. 2009 Apr 14;42(7):2658-2666. doi: 10.1021/ma802625d

Author

Jiang, Jia-Xing ; Trewin, Abbie ; Su, Fabing et al. / Microporous poly(tri(4-ethynylphenyl)amine) networks : synthesis, properties, and atomistic simulation. In: Macromolecules. 2009 ; Vol. 42, No. 7. pp. 2658-2666.

Bibtex

@article{c4f96f9a239e441287489811107006bf,
title = "Microporous poly(tri(4-ethynylphenyl)amine) networks: synthesis, properties, and atomistic simulation",
abstract = "Microporous poly(tri(4-ethynylphenyl)amine) networks were synthesized by palladium-catalyzed Sonogashira-Hagihara cross-coupling chemistry with apparent Brunauer-Emmet-Teller (BET) specific surface areas in the range 500-1100 m(2)/g. It was found that very fine synthetic control over physical properties such as BET surface area, Langmuir surface area, micropore surface area, micropore volume, and bulk density could be achieved by varying the average monomer strut length. The micropore structure and micropore surface area were rationalized by atomistic simulations for one network, NCMP-0, based on multiple physical characterization data.",
keywords = "COVALENT ORGANIC FRAMEWORKS, HYDROGEN STORAGE MATERIALS, SURFACE-AREA, INTRINSIC MICROPOROSITY, HYPERCROSSLINKED POLYSTYRENE, PHOTOVOLTAIC APPLICATIONS, COORDINATION POLYMERS, CONJUGATED POLYMERS, METHANE STORAGE, HYBRID SYSTEMS",
author = "Jia-Xing Jiang and Abbie Trewin and Fabing Su and Wood, {Colin D.} and Hongjun Niu and Jones, {James T. A.} and Khimyak, {Yaroslav Z.} and Cooper, {Andrew I.}",
year = "2009",
month = apr,
day = "14",
doi = "10.1021/ma802625d",
language = "English",
volume = "42",
pages = "2658--2666",
journal = "Macromolecules",
issn = "0024-9297",
publisher = "American Chemical Society",
number = "7",

}

RIS

TY - JOUR

T1 - Microporous poly(tri(4-ethynylphenyl)amine) networks

T2 - synthesis, properties, and atomistic simulation

AU - Jiang, Jia-Xing

AU - Trewin, Abbie

AU - Su, Fabing

AU - Wood, Colin D.

AU - Niu, Hongjun

AU - Jones, James T. A.

AU - Khimyak, Yaroslav Z.

AU - Cooper, Andrew I.

PY - 2009/4/14

Y1 - 2009/4/14

N2 - Microporous poly(tri(4-ethynylphenyl)amine) networks were synthesized by palladium-catalyzed Sonogashira-Hagihara cross-coupling chemistry with apparent Brunauer-Emmet-Teller (BET) specific surface areas in the range 500-1100 m(2)/g. It was found that very fine synthetic control over physical properties such as BET surface area, Langmuir surface area, micropore surface area, micropore volume, and bulk density could be achieved by varying the average monomer strut length. The micropore structure and micropore surface area were rationalized by atomistic simulations for one network, NCMP-0, based on multiple physical characterization data.

AB - Microporous poly(tri(4-ethynylphenyl)amine) networks were synthesized by palladium-catalyzed Sonogashira-Hagihara cross-coupling chemistry with apparent Brunauer-Emmet-Teller (BET) specific surface areas in the range 500-1100 m(2)/g. It was found that very fine synthetic control over physical properties such as BET surface area, Langmuir surface area, micropore surface area, micropore volume, and bulk density could be achieved by varying the average monomer strut length. The micropore structure and micropore surface area were rationalized by atomistic simulations for one network, NCMP-0, based on multiple physical characterization data.

KW - COVALENT ORGANIC FRAMEWORKS

KW - HYDROGEN STORAGE MATERIALS

KW - SURFACE-AREA

KW - INTRINSIC MICROPOROSITY

KW - HYPERCROSSLINKED POLYSTYRENE

KW - PHOTOVOLTAIC APPLICATIONS

KW - COORDINATION POLYMERS

KW - CONJUGATED POLYMERS

KW - METHANE STORAGE

KW - HYBRID SYSTEMS

U2 - 10.1021/ma802625d

DO - 10.1021/ma802625d

M3 - Journal article

VL - 42

SP - 2658

EP - 2666

JO - Macromolecules

JF - Macromolecules

SN - 0024-9297

IS - 7

ER -