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Molecular mapping of the acid catalysed dehydration of fructose

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Molecular mapping of the acid catalysed dehydration of fructose. / Akien, Geoffrey R.; Qi, Long; Horvath, Istvan T.
In: Chemical Communications, Vol. 48, No. 47, 2012, p. 5850-5852.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Akien, GR, Qi, L & Horvath, IT 2012, 'Molecular mapping of the acid catalysed dehydration of fructose', Chemical Communications, vol. 48, no. 47, pp. 5850-5852. https://doi.org/10.1039/c2cc31689g

APA

Akien, G. R., Qi, L., & Horvath, I. T. (2012). Molecular mapping of the acid catalysed dehydration of fructose. Chemical Communications, 48(47), 5850-5852. https://doi.org/10.1039/c2cc31689g

Vancouver

Akien GR, Qi L, Horvath IT. Molecular mapping of the acid catalysed dehydration of fructose. Chemical Communications. 2012;48(47):5850-5852. doi: 10.1039/c2cc31689g

Author

Akien, Geoffrey R. ; Qi, Long ; Horvath, Istvan T. / Molecular mapping of the acid catalysed dehydration of fructose. In: Chemical Communications. 2012 ; Vol. 48, No. 47. pp. 5850-5852.

Bibtex

@article{7eed05e6c52c4fbeb0c7ae3df282e0be,
title = "Molecular mapping of the acid catalysed dehydration of fructose",
abstract = "Several intermediates and different reaction paths were identified for the acid catalysed conversion of fructose to 5-( hydroxymethyl)-2- furaldehyde (HMF) in different solvents. The structural information combined with results of isotopic-labelling experiments allowed the determination of the irreversibility of the three steps from the fructofuranosyl oxocarbenium ion to HMF as well as the analogous pyranose route.",
keywords = "DIMETHYL-SULFOXIDE, PYRANOID TAUTOMERS, WATER, NMR, CHEMISTRY, MECHANISM, DIMETHYLSULFOXIDE, CELLULOSE, BIOFUELS, PYRIDINE",
author = "Akien, {Geoffrey R.} and Long Qi and Horvath, {Istvan T.}",
year = "2012",
doi = "10.1039/c2cc31689g",
language = "English",
volume = "48",
pages = "5850--5852",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "47",

}

RIS

TY - JOUR

T1 - Molecular mapping of the acid catalysed dehydration of fructose

AU - Akien, Geoffrey R.

AU - Qi, Long

AU - Horvath, Istvan T.

PY - 2012

Y1 - 2012

N2 - Several intermediates and different reaction paths were identified for the acid catalysed conversion of fructose to 5-( hydroxymethyl)-2- furaldehyde (HMF) in different solvents. The structural information combined with results of isotopic-labelling experiments allowed the determination of the irreversibility of the three steps from the fructofuranosyl oxocarbenium ion to HMF as well as the analogous pyranose route.

AB - Several intermediates and different reaction paths were identified for the acid catalysed conversion of fructose to 5-( hydroxymethyl)-2- furaldehyde (HMF) in different solvents. The structural information combined with results of isotopic-labelling experiments allowed the determination of the irreversibility of the three steps from the fructofuranosyl oxocarbenium ion to HMF as well as the analogous pyranose route.

KW - DIMETHYL-SULFOXIDE

KW - PYRANOID TAUTOMERS

KW - WATER

KW - NMR

KW - CHEMISTRY

KW - MECHANISM

KW - DIMETHYLSULFOXIDE

KW - CELLULOSE

KW - BIOFUELS

KW - PYRIDINE

U2 - 10.1039/c2cc31689g

DO - 10.1039/c2cc31689g

M3 - Journal article

VL - 48

SP - 5850

EP - 5852

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 47

ER -