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Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - On the Origin of Surface Ozone Episode in Shanghai over Yangtze River Delta during a Prolonged Heat Wave
AU - Wu, Jianbin
AU - Wang, Qian
AU - Chen, Huansheng
AU - Zhang, Yuqia
AU - Wild, Oliver
PY - 2017/10/31
Y1 - 2017/10/31
N2 - A heat wave with temperatures over 35°C and sunny stagnant meteorological conditions occurred in Shanghai from 27 July to 5 August 2015, leading to a sustained episode of high ozone lasting 12 days. We have conducted a detailed source apportionment of surface ozone, by precursor source category and region, using a photochemical transport model. In this episode, a southwesterly wind prevailed over the Yangtze River Delta, and therefore precursors from the local Shanghai region and the region immediately to the south of Shanghai are the two major contributors (in total 90%) to ozone in Shanghai. The source apportionment reveals that local industrial sources and energy/biogenic sources in neighbouring regions are the principal causes for the high levels of ozone. By examining the contributions from individual physical and chemical processes, we show that ozone concentrations start to rise rapidly in the morning because chemical production dominates as the solar radiation increases, and while there is little removal by deposition when ozone remains low. In general, chemical production, horizontal advection and vertical diffusion contribute to increase ozone concentration during daytime, and deposition and vertical advection reduce ozone concentrations.
AB - A heat wave with temperatures over 35°C and sunny stagnant meteorological conditions occurred in Shanghai from 27 July to 5 August 2015, leading to a sustained episode of high ozone lasting 12 days. We have conducted a detailed source apportionment of surface ozone, by precursor source category and region, using a photochemical transport model. In this episode, a southwesterly wind prevailed over the Yangtze River Delta, and therefore precursors from the local Shanghai region and the region immediately to the south of Shanghai are the two major contributors (in total 90%) to ozone in Shanghai. The source apportionment reveals that local industrial sources and energy/biogenic sources in neighbouring regions are the principal causes for the high levels of ozone. By examining the contributions from individual physical and chemical processes, we show that ozone concentrations start to rise rapidly in the morning because chemical production dominates as the solar radiation increases, and while there is little removal by deposition when ozone remains low. In general, chemical production, horizontal advection and vertical diffusion contribute to increase ozone concentration during daytime, and deposition and vertical advection reduce ozone concentrations.
KW - Ozone
KW - Source apportionment
KW - Process analysis
KW - Heatwaves
KW - Shanghai
KW - Modelling
KW - Meteorology
U2 - 10.4209/aaqr.2017.03.0101
DO - 10.4209/aaqr.2017.03.0101
M3 - Journal article
VL - 17
SP - 2804
EP - 2815
JO - Aerosol and Air Quality Research
JF - Aerosol and Air Quality Research
SN - 1680-8584
IS - 11
ER -