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Optimization study on preparation of amine functionalized sea mango (cerbera odollam) activated carbon for Carbon Dioxide (CO2) adsorption

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Optimization study on preparation of amine functionalized sea mango (cerbera odollam) activated carbon for Carbon Dioxide (CO2) adsorption. / Ali, Umi Fazara Md; Azmi, Nur Hidayah; Isa, Khairuddin Md et al.
In: Combustion Science and Technology, Vol. 190, No. 7, 03.07.2018, p. 1259-1282.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

Harvard

Ali, UFM, Azmi, NH, Isa, KM, Aroua, MK, Shien, TR & Khamidun, MH 2018, 'Optimization study on preparation of amine functionalized sea mango (cerbera odollam) activated carbon for Carbon Dioxide (CO2) adsorption', Combustion Science and Technology, vol. 190, no. 7, pp. 1259-1282. https://doi.org/10.1080/00102202.2018.1448393

APA

Ali, U. F. M., Azmi, N. H., Isa, K. M., Aroua, M. K., Shien, T. R., & Khamidun, M. H. (2018). Optimization study on preparation of amine functionalized sea mango (cerbera odollam) activated carbon for Carbon Dioxide (CO2) adsorption. Combustion Science and Technology, 190(7), 1259-1282. https://doi.org/10.1080/00102202.2018.1448393

Vancouver

Ali UFM, Azmi NH, Isa KM, Aroua MK, Shien TR, Khamidun MH. Optimization study on preparation of amine functionalized sea mango (cerbera odollam) activated carbon for Carbon Dioxide (CO2) adsorption. Combustion Science and Technology. 2018 Jul 3;190(7):1259-1282. Epub 2018 Mar 15. doi: 10.1080/00102202.2018.1448393

Author

Ali, Umi Fazara Md ; Azmi, Nur Hidayah ; Isa, Khairuddin Md et al. / Optimization study on preparation of amine functionalized sea mango (cerbera odollam) activated carbon for Carbon Dioxide (CO2) adsorption. In: Combustion Science and Technology. 2018 ; Vol. 190, No. 7. pp. 1259-1282.

Bibtex

@article{3f2168b0b9fa467183a5b54544d6535b,
title = "Optimization study on preparation of amine functionalized sea mango (cerbera odollam) activated carbon for Carbon Dioxide (CO2) adsorption",
abstract = "Activated carbon derived from sea mango (cerbera odollam), SMAC, was developed from phosphoric acid (H3PO4) activation. Box-Behnken Design (BBD) was employed to optimize the surface area of the SMAC. The tested factors were acid concentration (40 to 60%), carbonization temperature (400 to 600°C) and activation time (1 to 3 h). The optimized parameters were 53.75% H3PO4 concentration, 519.8°C of carbonization temperature and 2.3 h of activation time, which resulted in 857.93 m2/g of BET surface area. The performance of CO2 adsorption was investigated for modified and virgin SMAC. The impregnations of SMACs were done with different amines (AMP, PZ and MEA) to improve its natural adsorption ability and promote nitrogen functional group onto carbon surface with impregnation mass ratio of 2:5 (amine: activated carbon). The effects of adsorption parameters such as activated carbon properties, type of amine used, gas flow rate and adsorbent dosage on breakthrough curves and adsorption bed capacity were evaluated. Reduction in BET surface area indicates that the amine-based chemicals were successfully attached on carbon surface and thus blocked most of the pores on the SMAC particles. The modified surface of SMAC with AMP amine showed the best performance in CO2 adsorption and regeneration with adsorption bed capacity of 23.05 mgCO2/g sorbent. Successful CO2 adsorption via modified surface of SMAC suggested that it is viable to use sea mango as alternative precursor for activated carbon preparation and in application such as CO2 capture.",
keywords = "Activated carbon, Adsorption, Amine, Carbon dioxide, Cerbera odollam",
author = "Ali, {Umi Fazara Md} and Azmi, {Nur Hidayah} and Isa, {Khairuddin Md} and Aroua, {Mohamed Kheireddine} and Shien, {Tan Ru} and Khamidun, {Mohd Hairul}",
year = "2018",
month = jul,
day = "3",
doi = "10.1080/00102202.2018.1448393",
language = "English",
volume = "190",
pages = "1259--1282",
journal = "Combustion Science and Technology",
issn = "0010-2202",
publisher = "Taylor and Francis Ltd.",
number = "7",

}

RIS

TY - JOUR

T1 - Optimization study on preparation of amine functionalized sea mango (cerbera odollam) activated carbon for Carbon Dioxide (CO2) adsorption

AU - Ali, Umi Fazara Md

AU - Azmi, Nur Hidayah

AU - Isa, Khairuddin Md

AU - Aroua, Mohamed Kheireddine

AU - Shien, Tan Ru

AU - Khamidun, Mohd Hairul

PY - 2018/7/3

Y1 - 2018/7/3

N2 - Activated carbon derived from sea mango (cerbera odollam), SMAC, was developed from phosphoric acid (H3PO4) activation. Box-Behnken Design (BBD) was employed to optimize the surface area of the SMAC. The tested factors were acid concentration (40 to 60%), carbonization temperature (400 to 600°C) and activation time (1 to 3 h). The optimized parameters were 53.75% H3PO4 concentration, 519.8°C of carbonization temperature and 2.3 h of activation time, which resulted in 857.93 m2/g of BET surface area. The performance of CO2 adsorption was investigated for modified and virgin SMAC. The impregnations of SMACs were done with different amines (AMP, PZ and MEA) to improve its natural adsorption ability and promote nitrogen functional group onto carbon surface with impregnation mass ratio of 2:5 (amine: activated carbon). The effects of adsorption parameters such as activated carbon properties, type of amine used, gas flow rate and adsorbent dosage on breakthrough curves and adsorption bed capacity were evaluated. Reduction in BET surface area indicates that the amine-based chemicals were successfully attached on carbon surface and thus blocked most of the pores on the SMAC particles. The modified surface of SMAC with AMP amine showed the best performance in CO2 adsorption and regeneration with adsorption bed capacity of 23.05 mgCO2/g sorbent. Successful CO2 adsorption via modified surface of SMAC suggested that it is viable to use sea mango as alternative precursor for activated carbon preparation and in application such as CO2 capture.

AB - Activated carbon derived from sea mango (cerbera odollam), SMAC, was developed from phosphoric acid (H3PO4) activation. Box-Behnken Design (BBD) was employed to optimize the surface area of the SMAC. The tested factors were acid concentration (40 to 60%), carbonization temperature (400 to 600°C) and activation time (1 to 3 h). The optimized parameters were 53.75% H3PO4 concentration, 519.8°C of carbonization temperature and 2.3 h of activation time, which resulted in 857.93 m2/g of BET surface area. The performance of CO2 adsorption was investigated for modified and virgin SMAC. The impregnations of SMACs were done with different amines (AMP, PZ and MEA) to improve its natural adsorption ability and promote nitrogen functional group onto carbon surface with impregnation mass ratio of 2:5 (amine: activated carbon). The effects of adsorption parameters such as activated carbon properties, type of amine used, gas flow rate and adsorbent dosage on breakthrough curves and adsorption bed capacity were evaluated. Reduction in BET surface area indicates that the amine-based chemicals were successfully attached on carbon surface and thus blocked most of the pores on the SMAC particles. The modified surface of SMAC with AMP amine showed the best performance in CO2 adsorption and regeneration with adsorption bed capacity of 23.05 mgCO2/g sorbent. Successful CO2 adsorption via modified surface of SMAC suggested that it is viable to use sea mango as alternative precursor for activated carbon preparation and in application such as CO2 capture.

KW - Activated carbon

KW - Adsorption

KW - Amine

KW - Carbon dioxide

KW - Cerbera odollam

U2 - 10.1080/00102202.2018.1448393

DO - 10.1080/00102202.2018.1448393

M3 - Journal article

AN - SCOPUS:85044069803

VL - 190

SP - 1259

EP - 1282

JO - Combustion Science and Technology

JF - Combustion Science and Technology

SN - 0010-2202

IS - 7

ER -