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Phase behaviour of room temperature ionic liquid solutions: an unusually large co-solvent effect in (water plus ethanol)

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Journal publication date2002
JournalPhysical Chemistry Chemical Physics
Journal number10
Volume4
Number of pages3
Pages1701-1703
Original languageEnglish

Abstract

A surprising mixed solvent effect, both in its magnitude and direction, has been found in the phase diagram of the ternary mixture of ([C4mim][PF6]+(water+ethanol)). For a molar ratio of 1∶1 of water to ethanol, the co-solvent effect in the near-critical demixing temperature can be as large as 80 K.