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Polymeric material with metal-like conductivity for next generation organic electronic devices

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Polymeric material with metal-like conductivity for next generation organic electronic devices. / Fabretto, Manrico V.; Evans, Drew R.; Mueller, Michael et al.
In: Chemistry of Materials, Vol. 24, No. 20, 23.10.2012, p. 3998-4003.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

Harvard

Fabretto, MV, Evans, DR, Mueller, M, Zuber, K, Hojati-Talemi, P, Short, RD, Wallace, GG & Murphy, PJ 2012, 'Polymeric material with metal-like conductivity for next generation organic electronic devices', Chemistry of Materials, vol. 24, no. 20, pp. 3998-4003. https://doi.org/10.1021/cm302899v

APA

Fabretto, M. V., Evans, D. R., Mueller, M., Zuber, K., Hojati-Talemi, P., Short, R. D., Wallace, G. G., & Murphy, P. J. (2012). Polymeric material with metal-like conductivity for next generation organic electronic devices. Chemistry of Materials, 24(20), 3998-4003. https://doi.org/10.1021/cm302899v

Vancouver

Fabretto MV, Evans DR, Mueller M, Zuber K, Hojati-Talemi P, Short RD et al. Polymeric material with metal-like conductivity for next generation organic electronic devices. Chemistry of Materials. 2012 Oct 23;24(20):3998-4003. Epub 2012 Oct 1. doi: 10.1021/cm302899v

Author

Fabretto, Manrico V. ; Evans, Drew R. ; Mueller, Michael et al. / Polymeric material with metal-like conductivity for next generation organic electronic devices. In: Chemistry of Materials. 2012 ; Vol. 24, No. 20. pp. 3998-4003.

Bibtex

@article{e1a27b5267304ae994380fb94669c1a3,
title = "Polymeric material with metal-like conductivity for next generation organic electronic devices",
abstract = "The reduced pressure synthesis of poly(3,4-ethylenedioxythiophene) (PEDOT) with sheet-like morphology has been achieved with the introduction of an amphiphilic triblock copolymer into the oxidant thin film. Addition of the copolymer not only results in an oxidant thin film which remains liquid-like under reduced pressure but also induces structured growth during film formation. PEDOT films were polymerized using the vacuum vapor phase polymerization (VPP) technique, in which we show that maintaining a liquid-like state for the oxidant is essential. The resulting conductivity is equivalent to commercially available indium tin oxide (ITO) with concomitant optical transmission values. PEDOT films can be produced with a variety of thicknesses across a range of substrate materials from plastics to metals to ceramics, with sheet resistances down to 45 Omega/square (ca. 3400 S.cm(-1)), and transparency in the visible spectrum of >80% at 65 nm thickness. This compares favorably to ITO and its currently touted replacements.",
keywords = "vapor phase polymerization, PEDOT, high conductivity, organic electronics, VAPOR-PHASE POLYMERIZATION, ELECTRICAL-CONDUCTIVITY, THIN-FILMS, POLY(3,4-ETHYLENEDIOXYTHIOPHENE), TRANSPARENT, CRYSTALLINE, 3,4-ETHYLENEDIOXYTHIOPHENE, COPOLYMER, OXIDANT",
author = "Fabretto, {Manrico V.} and Evans, {Drew R.} and Michael Mueller and Kamil Zuber and Pejman Hojati-Talemi and Short, {Rob D.} and Wallace, {Gordon G.} and Murphy, {Peter J.}",
year = "2012",
month = oct,
day = "23",
doi = "10.1021/cm302899v",
language = "English",
volume = "24",
pages = "3998--4003",
journal = "Chemistry of Materials",
issn = "0897-4756",
publisher = "AMER CHEMICAL SOC",
number = "20",

}

RIS

TY - JOUR

T1 - Polymeric material with metal-like conductivity for next generation organic electronic devices

AU - Fabretto, Manrico V.

AU - Evans, Drew R.

AU - Mueller, Michael

AU - Zuber, Kamil

AU - Hojati-Talemi, Pejman

AU - Short, Rob D.

AU - Wallace, Gordon G.

AU - Murphy, Peter J.

PY - 2012/10/23

Y1 - 2012/10/23

N2 - The reduced pressure synthesis of poly(3,4-ethylenedioxythiophene) (PEDOT) with sheet-like morphology has been achieved with the introduction of an amphiphilic triblock copolymer into the oxidant thin film. Addition of the copolymer not only results in an oxidant thin film which remains liquid-like under reduced pressure but also induces structured growth during film formation. PEDOT films were polymerized using the vacuum vapor phase polymerization (VPP) technique, in which we show that maintaining a liquid-like state for the oxidant is essential. The resulting conductivity is equivalent to commercially available indium tin oxide (ITO) with concomitant optical transmission values. PEDOT films can be produced with a variety of thicknesses across a range of substrate materials from plastics to metals to ceramics, with sheet resistances down to 45 Omega/square (ca. 3400 S.cm(-1)), and transparency in the visible spectrum of >80% at 65 nm thickness. This compares favorably to ITO and its currently touted replacements.

AB - The reduced pressure synthesis of poly(3,4-ethylenedioxythiophene) (PEDOT) with sheet-like morphology has been achieved with the introduction of an amphiphilic triblock copolymer into the oxidant thin film. Addition of the copolymer not only results in an oxidant thin film which remains liquid-like under reduced pressure but also induces structured growth during film formation. PEDOT films were polymerized using the vacuum vapor phase polymerization (VPP) technique, in which we show that maintaining a liquid-like state for the oxidant is essential. The resulting conductivity is equivalent to commercially available indium tin oxide (ITO) with concomitant optical transmission values. PEDOT films can be produced with a variety of thicknesses across a range of substrate materials from plastics to metals to ceramics, with sheet resistances down to 45 Omega/square (ca. 3400 S.cm(-1)), and transparency in the visible spectrum of >80% at 65 nm thickness. This compares favorably to ITO and its currently touted replacements.

KW - vapor phase polymerization

KW - PEDOT

KW - high conductivity

KW - organic electronics

KW - VAPOR-PHASE POLYMERIZATION

KW - ELECTRICAL-CONDUCTIVITY

KW - THIN-FILMS

KW - POLY(3,4-ETHYLENEDIOXYTHIOPHENE)

KW - TRANSPARENT

KW - CRYSTALLINE

KW - 3,4-ETHYLENEDIOXYTHIOPHENE

KW - COPOLYMER

KW - OXIDANT

U2 - 10.1021/cm302899v

DO - 10.1021/cm302899v

M3 - Journal article

VL - 24

SP - 3998

EP - 4003

JO - Chemistry of Materials

JF - Chemistry of Materials

SN - 0897-4756

IS - 20

ER -