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Porous organic molecular solids by dynamic covalent scrambling

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Porous organic molecular solids by dynamic covalent scrambling. / Jiang, Shan; Jones, James T. A.; Hasell, Tom et al.
In: Nature Communications, Vol. 2, No. 2, 207, 02.2011.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Jiang, S, Jones, JTA, Hasell, T, Blythe, CE, Adams, DJ, Trewin, A & Cooper, AI 2011, 'Porous organic molecular solids by dynamic covalent scrambling', Nature Communications, vol. 2, no. 2, 207. https://doi.org/10.1038/ncomms1207

APA

Jiang, S., Jones, J. T. A., Hasell, T., Blythe, C. E., Adams, D. J., Trewin, A., & Cooper, A. I. (2011). Porous organic molecular solids by dynamic covalent scrambling. Nature Communications, 2(2), Article 207. https://doi.org/10.1038/ncomms1207

Vancouver

Jiang S, Jones JTA, Hasell T, Blythe CE, Adams DJ, Trewin A et al. Porous organic molecular solids by dynamic covalent scrambling. Nature Communications. 2011 Feb;2(2):207. doi: 10.1038/ncomms1207

Author

Jiang, Shan ; Jones, James T. A. ; Hasell, Tom et al. / Porous organic molecular solids by dynamic covalent scrambling. In: Nature Communications. 2011 ; Vol. 2, No. 2.

Bibtex

@article{5ea7cb4e5530450681aa8847baf379f3,
title = "Porous organic molecular solids by dynamic covalent scrambling",
abstract = "The main strategy for constructing porous solids from discrete organic molecules is crystal engineering, which involves forming regular crystalline arrays. Here, we present a chemical approach for desymmetrizing organic cages by dynamic covalent scrambling reactions. This leads to molecules with a distribution of shapes which cannot pack effectively and, hence, do not crystallize, creating porosity in the amorphous solid. The porous properties can be fine tuned by varying the ratio of reagents in the scrambling reaction, and this allows the preparation of materials with high gas selectivities. The molecular engineering of porous amorphous solids complements crystal engineering strategies and may have advantages in some applications, for example, in the compatibilization of functionalities that do not readily cocrystallize.",
keywords = "INTRINSIC MICROPOROSITY PIMS, SORPTION PROPERTIES, HYDROGEN STORAGE, POLYMER NETWORKS, GAS-ADSORPTION, SURFACE-AREAS, FORCE-FIELD, FRAMEWORKS, CHEMISTRY, CRYSTAL",
author = "Shan Jiang and Jones, {James T. A.} and Tom Hasell and Blythe, {Charlotte E.} and Adams, {Dave J.} and Abbie Trewin and Cooper, {Andrew I.}",
year = "2011",
month = feb,
doi = "10.1038/ncomms1207",
language = "English",
volume = "2",
journal = "Nature Communications",
issn = "2041-1723",
publisher = "Nature Publishing Group",
number = "2",

}

RIS

TY - JOUR

T1 - Porous organic molecular solids by dynamic covalent scrambling

AU - Jiang, Shan

AU - Jones, James T. A.

AU - Hasell, Tom

AU - Blythe, Charlotte E.

AU - Adams, Dave J.

AU - Trewin, Abbie

AU - Cooper, Andrew I.

PY - 2011/2

Y1 - 2011/2

N2 - The main strategy for constructing porous solids from discrete organic molecules is crystal engineering, which involves forming regular crystalline arrays. Here, we present a chemical approach for desymmetrizing organic cages by dynamic covalent scrambling reactions. This leads to molecules with a distribution of shapes which cannot pack effectively and, hence, do not crystallize, creating porosity in the amorphous solid. The porous properties can be fine tuned by varying the ratio of reagents in the scrambling reaction, and this allows the preparation of materials with high gas selectivities. The molecular engineering of porous amorphous solids complements crystal engineering strategies and may have advantages in some applications, for example, in the compatibilization of functionalities that do not readily cocrystallize.

AB - The main strategy for constructing porous solids from discrete organic molecules is crystal engineering, which involves forming regular crystalline arrays. Here, we present a chemical approach for desymmetrizing organic cages by dynamic covalent scrambling reactions. This leads to molecules with a distribution of shapes which cannot pack effectively and, hence, do not crystallize, creating porosity in the amorphous solid. The porous properties can be fine tuned by varying the ratio of reagents in the scrambling reaction, and this allows the preparation of materials with high gas selectivities. The molecular engineering of porous amorphous solids complements crystal engineering strategies and may have advantages in some applications, for example, in the compatibilization of functionalities that do not readily cocrystallize.

KW - INTRINSIC MICROPOROSITY PIMS

KW - SORPTION PROPERTIES

KW - HYDROGEN STORAGE

KW - POLYMER NETWORKS

KW - GAS-ADSORPTION

KW - SURFACE-AREAS

KW - FORCE-FIELD

KW - FRAMEWORKS

KW - CHEMISTRY

KW - CRYSTAL

U2 - 10.1038/ncomms1207

DO - 10.1038/ncomms1207

M3 - Journal article

VL - 2

JO - Nature Communications

JF - Nature Communications

SN - 2041-1723

IS - 2

M1 - 207

ER -