Polycyclic aromatic compounds (PACs) pollution has been the focus of environmental research, mostly due to their mutagenicity, carcinogenicity, teratogenicity and genotoxicity. Concentrations of polycyclic aromatic hydrocarbons (PAHs) and the nitrogen-containing analogues (N-PAHs) (which tend to accumulate in sediments rather than water) was measured in 2 cm intervals segments from Bonny Estuary, Niger Delta using GC–MS. Data showed that PAHs/N-PAHs levels ranged from 8699 to 22,528 µg/kg and 503–2020 µg/kg, respectively. Furthermore, the data revealed that ƩPAHs level in the estuarine segments was > 45% higher than DPR/EGASPIN intervention limit. This gives insight on PAHs/N-PAHs contamination in the oil rich region.