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  • Franckevicius Manuscript REVISED FINAL

    Rights statement: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acs.orglett.5b01979

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Regioswitchable palladium-catalyzed decarboxylative coupling of 1,3-dicarbonyl compounds

Research output: Contribution to journalJournal article

Published
<mark>Journal publication date</mark>27/07/2015
<mark>Journal</mark>Organic Letters
Issue number15
Volume17
Number of pages4
Pages (from-to)3926-3929
Publication statusPublished
Original languageEnglish

Abstract

A palladium-catalyzed chemo- and regioselective coupling of 1,3-dicarbonyl compounds via an allylic linker has been developed. This reaction, which displays broad substrate scope, forms two C−C bonds and installs two all-carbon quaternary centers. The regioselectivity of the reaction can be predictably controlled by utilizing an enol carbonate of one of the coupling partners.

Bibliographic note

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acs.orglett.5b01979