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    Rights statement: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acs.orglett.5b01979

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Regioswitchable palladium-catalyzed decarboxylative coupling of 1,3-dicarbonyl compounds

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Regioswitchable palladium-catalyzed decarboxylative coupling of 1,3-dicarbonyl compounds. / Kenny, Miles; Christensen, Jeppe; Coles, Simon et al.
In: Organic Letters, Vol. 17, No. 15, 27.07.2015, p. 3926-3929.

Research output: Contribution to Journal/MagazineJournal articlepeer-review

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Kenny M, Christensen J, Coles S, Franckevicius V. Regioswitchable palladium-catalyzed decarboxylative coupling of 1,3-dicarbonyl compounds. Organic Letters. 2015 Jul 27;17(15):3926-3929. doi: 10.1021/acs.orglett.5b01979

Author

Kenny, Miles ; Christensen, Jeppe ; Coles, Simon et al. / Regioswitchable palladium-catalyzed decarboxylative coupling of 1,3-dicarbonyl compounds. In: Organic Letters. 2015 ; Vol. 17, No. 15. pp. 3926-3929.

Bibtex

@article{84bcbaefd52747fe82d0f69f01008698,
title = "Regioswitchable palladium-catalyzed decarboxylative coupling of 1,3-dicarbonyl compounds",
abstract = "A palladium-catalyzed chemo- and regioselective coupling of 1,3-dicarbonyl compounds via an allylic linker has been developed. This reaction, which displays broad substrate scope, forms two C−C bonds and installs two all-carbon quaternary centers. The regioselectivity of the reaction can be predictably controlled by utilizing an enol carbonate of one of the coupling partners.",
author = "Miles Kenny and Jeppe Christensen and Simon Coles and Vilius Franckevicius",
note = " This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters], copyright {\textcopyright} American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acs.orglett.5b01979",
year = "2015",
month = jul,
day = "27",
doi = "10.1021/acs.orglett.5b01979",
language = "English",
volume = "17",
pages = "3926--3929",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "15",

}

RIS

TY - JOUR

T1 - Regioswitchable palladium-catalyzed decarboxylative coupling of 1,3-dicarbonyl compounds

AU - Kenny, Miles

AU - Christensen, Jeppe

AU - Coles, Simon

AU - Franckevicius, Vilius

N1 - This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acs.orglett.5b01979

PY - 2015/7/27

Y1 - 2015/7/27

N2 - A palladium-catalyzed chemo- and regioselective coupling of 1,3-dicarbonyl compounds via an allylic linker has been developed. This reaction, which displays broad substrate scope, forms two C−C bonds and installs two all-carbon quaternary centers. The regioselectivity of the reaction can be predictably controlled by utilizing an enol carbonate of one of the coupling partners.

AB - A palladium-catalyzed chemo- and regioselective coupling of 1,3-dicarbonyl compounds via an allylic linker has been developed. This reaction, which displays broad substrate scope, forms two C−C bonds and installs two all-carbon quaternary centers. The regioselectivity of the reaction can be predictably controlled by utilizing an enol carbonate of one of the coupling partners.

U2 - 10.1021/acs.orglett.5b01979

DO - 10.1021/acs.orglett.5b01979

M3 - Journal article

VL - 17

SP - 3926

EP - 3929

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 15

ER -