Rights statement: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acs.orglett.5b01979
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Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
}
TY - JOUR
T1 - Regioswitchable palladium-catalyzed decarboxylative coupling of 1,3-dicarbonyl compounds
AU - Kenny, Miles
AU - Christensen, Jeppe
AU - Coles, Simon
AU - Franckevicius, Vilius
N1 - This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acs.orglett.5b01979
PY - 2015/7/27
Y1 - 2015/7/27
N2 - A palladium-catalyzed chemo- and regioselective coupling of 1,3-dicarbonyl compounds via an allylic linker has been developed. This reaction, which displays broad substrate scope, forms two C−C bonds and installs two all-carbon quaternary centers. The regioselectivity of the reaction can be predictably controlled by utilizing an enol carbonate of one of the coupling partners.
AB - A palladium-catalyzed chemo- and regioselective coupling of 1,3-dicarbonyl compounds via an allylic linker has been developed. This reaction, which displays broad substrate scope, forms two C−C bonds and installs two all-carbon quaternary centers. The regioselectivity of the reaction can be predictably controlled by utilizing an enol carbonate of one of the coupling partners.
U2 - 10.1021/acs.orglett.5b01979
DO - 10.1021/acs.orglett.5b01979
M3 - Journal article
VL - 17
SP - 3926
EP - 3929
JO - Organic Letters
JF - Organic Letters
SN - 1523-7060
IS - 15
ER -