Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Seasonality of air-forest canopy exchange of persistent organic pollutants
AU - Nizzetto, Luca
AU - Jarvis, Andrew
AU - Brivio, Pietro A.
AU - Jones, Kevin C.
AU - Di Guardo, Antonio
PY - 2008/12/1
Y1 - 2008/12/1
N2 - Forest canopies represent an extensive organic surface available for partitioning of semivolatile organic pollutants with the atmosphere. To date, the ability of forests to sequester such compounds (the so-called “forest filter effect”) has been investigated using indirect methods that yield time integrated deposition fluxes and scenario-dependent deposition velocities. In the present study, experimental data collected at three different alpine forest sites were used to assess the dynamics of PCB deposition fluxes (F, ng m−2 d−1) during the growing season. Estimated values of F were consistent with previously reported data. Furthermore, this study showed that maximum levels of F in late spring can be a factor of 1.4−3.4 higher than their seasonal mean value. These data, in conjunction with a simple model framework that includes the main forcing parameters of air concentration, temperature, foliage structure, and biomass dynamics, are used to estimate the plant−air mass transfer coefficient (kU, m d−1) and its variation with time in one of the forests. kU did not appear to significantly vary during the season, and its mean seasonal value ranged between 43 and 95 m d−1 for selected compounds. The proposed framework was successfully applied to predict the variation in canopy concentration with time in the other two forests.
AB - Forest canopies represent an extensive organic surface available for partitioning of semivolatile organic pollutants with the atmosphere. To date, the ability of forests to sequester such compounds (the so-called “forest filter effect”) has been investigated using indirect methods that yield time integrated deposition fluxes and scenario-dependent deposition velocities. In the present study, experimental data collected at three different alpine forest sites were used to assess the dynamics of PCB deposition fluxes (F, ng m−2 d−1) during the growing season. Estimated values of F were consistent with previously reported data. Furthermore, this study showed that maximum levels of F in late spring can be a factor of 1.4−3.4 higher than their seasonal mean value. These data, in conjunction with a simple model framework that includes the main forcing parameters of air concentration, temperature, foliage structure, and biomass dynamics, are used to estimate the plant−air mass transfer coefficient (kU, m d−1) and its variation with time in one of the forests. kU did not appear to significantly vary during the season, and its mean seasonal value ranged between 43 and 95 m d−1 for selected compounds. The proposed framework was successfully applied to predict the variation in canopy concentration with time in the other two forests.
UR - http://www.scopus.com/inward/record.url?scp=57449087897&partnerID=8YFLogxK
U2 - 10.1021/es802019g
DO - 10.1021/es802019g
M3 - Journal article
VL - 42
SP - 8778
EP - 8783
JO - Environmental Science and Technology
JF - Environmental Science and Technology
SN - 0013-936X
IS - 23
ER -