Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Selective gas sorption in a [2+3] 'propeller' cage crystal
AU - Jiang, Shan
AU - Bacsa, John
AU - Wu, Xiaofeng
AU - Jones, James T. A.
AU - Dawson, Robert
AU - Trewin, Abbie
AU - Adams, Dave J.
AU - Cooper, Andrew I.
PY - 2011
Y1 - 2011
N2 - A [2 + 3] organic cage compound based on the condensation reaction of 1,3,5-tri(4-formylphenyl)benzene with 1,5-pentanediamine was synthesized. The resulting porous molecular crystal demonstrates selective adsorption of hydrogen and carbon dioxide over nitrogen. As for porous polymer membranes, a trade-off between sorption capacity and selectivity is observed for materials in this class.
AB - A [2 + 3] organic cage compound based on the condensation reaction of 1,3,5-tri(4-formylphenyl)benzene with 1,5-pentanediamine was synthesized. The resulting porous molecular crystal demonstrates selective adsorption of hydrogen and carbon dioxide over nitrogen. As for porous polymer membranes, a trade-off between sorption capacity and selectivity is observed for materials in this class.
KW - MOLECULAR POROUS MATERIAL
KW - ADSORPTION
KW - FRAMEWORKS
KW - POROSITY
KW - DESIGN
KW - CO2
U2 - 10.1039/c1cc12460a
DO - 10.1039/c1cc12460a
M3 - Journal article
VL - 47
SP - 8919
EP - 8921
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 31
ER -