Home > Research > Publications & Outputs > Solubility of high-value compounds in ethyl lac...

Research

Associated organisational units

Links

Text available via DOI:

Keywords

View graph of relations

Solubility of high-value compounds in ethyl lactate: measurements and modelling

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Published

Standard

Solubility of high-value compounds in ethyl lactate: measurements and modelling. / Manic, Marina S.; Villanueva, David; Fornari, Tiziana et al.
In: Journal of Chemical Thermodynamics, Vol. 48, 05.2012, p. 93-100.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Manic, MS, Villanueva, D, Fornari, T, Queimada, AJ, Macedo, EA & Najdanovic, V 2012, 'Solubility of high-value compounds in ethyl lactate: measurements and modelling', Journal of Chemical Thermodynamics, vol. 48, pp. 93-100. https://doi.org/10.1016/j.jct.2011.12.005

APA

Manic, M. S., Villanueva, D., Fornari, T., Queimada, A. J., Macedo, E. A., & Najdanovic, V. (2012). Solubility of high-value compounds in ethyl lactate: measurements and modelling. Journal of Chemical Thermodynamics, 48, 93-100. https://doi.org/10.1016/j.jct.2011.12.005

Vancouver

Manic MS, Villanueva D, Fornari T, Queimada AJ, Macedo EA, Najdanovic V. Solubility of high-value compounds in ethyl lactate: measurements and modelling. Journal of Chemical Thermodynamics. 2012 May;48:93-100. doi: 10.1016/j.jct.2011.12.005

Author

Manic, Marina S. ; Villanueva, David ; Fornari, Tiziana et al. / Solubility of high-value compounds in ethyl lactate : measurements and modelling. In: Journal of Chemical Thermodynamics. 2012 ; Vol. 48. pp. 93-100.

Bibtex

@article{4c915a198e38419e9c2ac2e8cffe2c83,
title = "Solubility of high-value compounds in ethyl lactate: measurements and modelling",
abstract = "(Solid + liquid) equilibria of binary mixtures containing high-value compounds and ethyl lactate were studied. Using the gravimetric method, the solubility of various solutes such as caffeine, vanillic acid, ferulic acid, caffeic acid and thymol in ethyl lactate was measured as a function of temperature over the range of (298.2 to 343.2) K, at atmospheric pressure. The differences in solubility of a given solute in water-saturated and dry ethyl lactate were observed. The deviation of these binary systems from ideal mixture behaviour was discussed. In order to understand the solubilization process, melting properties of pure solutes were determined by differential scanning calorimetry (DSC). The solubility data obtained were represented using UNIQUAC and UNIFAC-based models as well as with the Cubic-Plus-Association (CPA) equation of state. The results of the modeling indicate that these models are the appropriate tools for representing the solubility behaviour of various solutes in ethyl lactate. (C) 2011 Elsevier Ltd. All rights reserved.",
keywords = "FERULIC ACID, EQUATION-OF-STATE, UNIFAC, Solubility, UNIQUAC, EXTRACTION, Cubic-Plus-Association equation of state, PHASE-BEHAVIOR, HEAT-CAPACITY, OLIVE OIL, ORGANIC-COMPOUNDS, Green solvents, VANILLIC ACID, High-value solutes, IONIC LIQUIDS, PHENOLIC-COMPOUNDS",
author = "Manic, {Marina S.} and David Villanueva and Tiziana Fornari and Queimada, {Antonio J.} and Macedo, {Eugenia A.} and Vesna Najdanovic",
year = "2012",
month = may,
doi = "10.1016/j.jct.2011.12.005",
language = "English",
volume = "48",
pages = "93--100",
journal = "Journal of Chemical Thermodynamics",
issn = "0021-9614",
publisher = "Academic Press Inc.",

}

RIS

TY - JOUR

T1 - Solubility of high-value compounds in ethyl lactate

T2 - measurements and modelling

AU - Manic, Marina S.

AU - Villanueva, David

AU - Fornari, Tiziana

AU - Queimada, Antonio J.

AU - Macedo, Eugenia A.

AU - Najdanovic, Vesna

PY - 2012/5

Y1 - 2012/5

N2 - (Solid + liquid) equilibria of binary mixtures containing high-value compounds and ethyl lactate were studied. Using the gravimetric method, the solubility of various solutes such as caffeine, vanillic acid, ferulic acid, caffeic acid and thymol in ethyl lactate was measured as a function of temperature over the range of (298.2 to 343.2) K, at atmospheric pressure. The differences in solubility of a given solute in water-saturated and dry ethyl lactate were observed. The deviation of these binary systems from ideal mixture behaviour was discussed. In order to understand the solubilization process, melting properties of pure solutes were determined by differential scanning calorimetry (DSC). The solubility data obtained were represented using UNIQUAC and UNIFAC-based models as well as with the Cubic-Plus-Association (CPA) equation of state. The results of the modeling indicate that these models are the appropriate tools for representing the solubility behaviour of various solutes in ethyl lactate. (C) 2011 Elsevier Ltd. All rights reserved.

AB - (Solid + liquid) equilibria of binary mixtures containing high-value compounds and ethyl lactate were studied. Using the gravimetric method, the solubility of various solutes such as caffeine, vanillic acid, ferulic acid, caffeic acid and thymol in ethyl lactate was measured as a function of temperature over the range of (298.2 to 343.2) K, at atmospheric pressure. The differences in solubility of a given solute in water-saturated and dry ethyl lactate were observed. The deviation of these binary systems from ideal mixture behaviour was discussed. In order to understand the solubilization process, melting properties of pure solutes were determined by differential scanning calorimetry (DSC). The solubility data obtained were represented using UNIQUAC and UNIFAC-based models as well as with the Cubic-Plus-Association (CPA) equation of state. The results of the modeling indicate that these models are the appropriate tools for representing the solubility behaviour of various solutes in ethyl lactate. (C) 2011 Elsevier Ltd. All rights reserved.

KW - FERULIC ACID

KW - EQUATION-OF-STATE

KW - UNIFAC

KW - Solubility

KW - UNIQUAC

KW - EXTRACTION

KW - Cubic-Plus-Association equation of state

KW - PHASE-BEHAVIOR

KW - HEAT-CAPACITY

KW - OLIVE OIL

KW - ORGANIC-COMPOUNDS

KW - Green solvents

KW - VANILLIC ACID

KW - High-value solutes

KW - IONIC LIQUIDS

KW - PHENOLIC-COMPOUNDS

U2 - 10.1016/j.jct.2011.12.005

DO - 10.1016/j.jct.2011.12.005

M3 - Journal article

VL - 48

SP - 93

EP - 100

JO - Journal of Chemical Thermodynamics

JF - Journal of Chemical Thermodynamics

SN - 0021-9614

ER -