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Sorption effect on kinetics of etherification of tert-amyl alcohol and ethanol

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Sorption effect on kinetics of etherification of tert-amyl alcohol and ethanol. / Aiouache, Farid; Goto, Shigeo.
In: Chemical Engineering Science, Vol. 58, No. 10, 05.2003, p. 2065-2077.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Aiouache, F & Goto, S 2003, 'Sorption effect on kinetics of etherification of tert-amyl alcohol and ethanol', Chemical Engineering Science, vol. 58, no. 10, pp. 2065-2077. https://doi.org/10.1016/S0009-2509(03)00052-6

APA

Aiouache, F., & Goto, S. (2003). Sorption effect on kinetics of etherification of tert-amyl alcohol and ethanol. Chemical Engineering Science, 58(10), 2065-2077. https://doi.org/10.1016/S0009-2509(03)00052-6

Vancouver

Aiouache F, Goto S. Sorption effect on kinetics of etherification of tert-amyl alcohol and ethanol. Chemical Engineering Science. 2003 May;58(10):2065-2077. doi: 10.1016/S0009-2509(03)00052-6

Author

Aiouache, Farid ; Goto, Shigeo. / Sorption effect on kinetics of etherification of tert-amyl alcohol and ethanol. In: Chemical Engineering Science. 2003 ; Vol. 58, No. 10. pp. 2065-2077.

Bibtex

@article{5deee46a57254eb18ecd080f31c425ff,
title = "Sorption effect on kinetics of etherification of tert-amyl alcohol and ethanol",
abstract = "The kinetics of the etherification of tert-amyl alcohol with ethanol, catalysed by a strong ion-exchange resin, Amberlyst 15, has been studied in a batch reactor at temperatures between 323 and 353 K and at a pressure of 0.8 MPa. The kinetics was described by a coupled sorption-reaction model. Flory-Huggins (F-H) model was used to predict the solubility of reaction components in the resin phase at 278 K (non-reactive conditions). Both sorption interaction parameters of F-H model and kinetic constants were determined by non-linear least-squares method. Langmuir-Hinshelwood (L-H) and power law (PL) kinetic models were compared with the experimental data. Although both the models were found to be equally successful, L-H model has shown a slightly better representation than PL model. (C) 2003 Elsevier Science Ltd. All rights reserved.",
keywords = "Sorption equilibrium, Etheri#cation, kinetics, Modelling, Oxygenates;, Ion-exchange resin;",
author = "Farid Aiouache and Shigeo Goto",
year = "2003",
month = may,
doi = "10.1016/S0009-2509(03)00052-6",
language = "English",
volume = "58",
pages = "2065--2077",
journal = "Chemical Engineering Science",
issn = "0009-2509",
publisher = "Elsevier BV",
number = "10",

}

RIS

TY - JOUR

T1 - Sorption effect on kinetics of etherification of tert-amyl alcohol and ethanol

AU - Aiouache, Farid

AU - Goto, Shigeo

PY - 2003/5

Y1 - 2003/5

N2 - The kinetics of the etherification of tert-amyl alcohol with ethanol, catalysed by a strong ion-exchange resin, Amberlyst 15, has been studied in a batch reactor at temperatures between 323 and 353 K and at a pressure of 0.8 MPa. The kinetics was described by a coupled sorption-reaction model. Flory-Huggins (F-H) model was used to predict the solubility of reaction components in the resin phase at 278 K (non-reactive conditions). Both sorption interaction parameters of F-H model and kinetic constants were determined by non-linear least-squares method. Langmuir-Hinshelwood (L-H) and power law (PL) kinetic models were compared with the experimental data. Although both the models were found to be equally successful, L-H model has shown a slightly better representation than PL model. (C) 2003 Elsevier Science Ltd. All rights reserved.

AB - The kinetics of the etherification of tert-amyl alcohol with ethanol, catalysed by a strong ion-exchange resin, Amberlyst 15, has been studied in a batch reactor at temperatures between 323 and 353 K and at a pressure of 0.8 MPa. The kinetics was described by a coupled sorption-reaction model. Flory-Huggins (F-H) model was used to predict the solubility of reaction components in the resin phase at 278 K (non-reactive conditions). Both sorption interaction parameters of F-H model and kinetic constants were determined by non-linear least-squares method. Langmuir-Hinshelwood (L-H) and power law (PL) kinetic models were compared with the experimental data. Although both the models were found to be equally successful, L-H model has shown a slightly better representation than PL model. (C) 2003 Elsevier Science Ltd. All rights reserved.

KW - Sorption equilibrium

KW - Etheri#cation

KW - kinetics

KW - Modelling

KW - Oxygenates;

KW - Ion-exchange resin;

U2 - 10.1016/S0009-2509(03)00052-6

DO - 10.1016/S0009-2509(03)00052-6

M3 - Journal article

VL - 58

SP - 2065

EP - 2077

JO - Chemical Engineering Science

JF - Chemical Engineering Science

SN - 0009-2509

IS - 10

ER -