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Styrene carbonate synthesis from CO2 using tetrabutylammonium bromide as a non-supported heterogeneous catalyst phase

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Styrene carbonate synthesis from CO2 using tetrabutylammonium bromide as a non-supported heterogeneous catalyst phase. / Montoya, Carmen A.; B. Paninho, Ana; Pedro M., Felix et al.
In: Journal of Supercritical Fluids, Vol. 100, 05.2015, p. 155-159.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Montoya, CA, B. Paninho, A, Pedro M., F, Zakrzewska, ME, Joaquim, V, Najdanovic-Visak, V & Nunes, AVM 2015, 'Styrene carbonate synthesis from CO2 using tetrabutylammonium bromide as a non-supported heterogeneous catalyst phase', Journal of Supercritical Fluids, vol. 100, pp. 155-159. https://doi.org/10.1016/j.supflu.2015.01.027

APA

Montoya, C. A., B. Paninho, A., Pedro M., F., Zakrzewska, M. E., Joaquim, V., Najdanovic-Visak, V., & Nunes, A. V. M. (2015). Styrene carbonate synthesis from CO2 using tetrabutylammonium bromide as a non-supported heterogeneous catalyst phase. Journal of Supercritical Fluids, 100, 155-159. https://doi.org/10.1016/j.supflu.2015.01.027

Vancouver

Montoya CA, B. Paninho A, Pedro M. F, Zakrzewska ME, Joaquim V, Najdanovic-Visak V et al. Styrene carbonate synthesis from CO2 using tetrabutylammonium bromide as a non-supported heterogeneous catalyst phase. Journal of Supercritical Fluids. 2015 May;100:155-159. Epub 2015 Feb 8. doi: 10.1016/j.supflu.2015.01.027

Author

Montoya, Carmen A. ; B. Paninho, Ana ; Pedro M., Felix et al. / Styrene carbonate synthesis from CO2 using tetrabutylammonium bromide as a non-supported heterogeneous catalyst phase. In: Journal of Supercritical Fluids. 2015 ; Vol. 100. pp. 155-159.

Bibtex

@article{edc92d7dee134f9db232b0952117c682,
title = "Styrene carbonate synthesis from CO2 using tetrabutylammonium bromide as a non-supported heterogeneous catalyst phase",
abstract = "The production of cyclic styrene carbonate from CO2 cycloaddition to styrene oxide, using tetrabutylammonium bromide (TBABr) as catalyst, was investigated. Two different reaction systems, a CO2-rich and an epoxide-rich were studied. Reactions were performed in a visual high pressure cell, at different temperatures (313.2, 333.2, and 353.2 K) and pressures (0.5-18 MPa). High pressure phase behaviour manipulation of the reaction system was explored to shift catalysis from homogeneous to heterogeneous, by changing operation conditions. Styrene carbonate formation was monitored quantitatively by using 1H-NMR spectroscopy.",
author = "Montoya, {Carmen A.} and {B. Paninho}, Ana and {Pedro M.}, Felix and Zakrzewska, {Malgorzata E.} and Vital Joaquim and Vesna Najdanovic-Visak and Nunes, {Ana V.M.}",
year = "2015",
month = may,
doi = "10.1016/j.supflu.2015.01.027",
language = "English",
volume = "100",
pages = "155--159",
journal = "Journal of Supercritical Fluids",
issn = "0896-8446",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Styrene carbonate synthesis from CO2 using tetrabutylammonium bromide as a non-supported heterogeneous catalyst phase

AU - Montoya, Carmen A.

AU - B. Paninho, Ana

AU - Pedro M., Felix

AU - Zakrzewska, Malgorzata E.

AU - Joaquim, Vital

AU - Najdanovic-Visak, Vesna

AU - Nunes, Ana V.M.

PY - 2015/5

Y1 - 2015/5

N2 - The production of cyclic styrene carbonate from CO2 cycloaddition to styrene oxide, using tetrabutylammonium bromide (TBABr) as catalyst, was investigated. Two different reaction systems, a CO2-rich and an epoxide-rich were studied. Reactions were performed in a visual high pressure cell, at different temperatures (313.2, 333.2, and 353.2 K) and pressures (0.5-18 MPa). High pressure phase behaviour manipulation of the reaction system was explored to shift catalysis from homogeneous to heterogeneous, by changing operation conditions. Styrene carbonate formation was monitored quantitatively by using 1H-NMR spectroscopy.

AB - The production of cyclic styrene carbonate from CO2 cycloaddition to styrene oxide, using tetrabutylammonium bromide (TBABr) as catalyst, was investigated. Two different reaction systems, a CO2-rich and an epoxide-rich were studied. Reactions were performed in a visual high pressure cell, at different temperatures (313.2, 333.2, and 353.2 K) and pressures (0.5-18 MPa). High pressure phase behaviour manipulation of the reaction system was explored to shift catalysis from homogeneous to heterogeneous, by changing operation conditions. Styrene carbonate formation was monitored quantitatively by using 1H-NMR spectroscopy.

U2 - 10.1016/j.supflu.2015.01.027

DO - 10.1016/j.supflu.2015.01.027

M3 - Journal article

VL - 100

SP - 155

EP - 159

JO - Journal of Supercritical Fluids

JF - Journal of Supercritical Fluids

SN - 0896-8446

ER -