Home > Research > Publications & Outputs > Syntheses and structures of iron(III) complexes...
View graph of relations

Syntheses and structures of iron(III) complexes of simple N-donor ligands

Research output: Contribution to journalJournal article


<mark>Journal publication date</mark>1/09/2002
Issue number20
Number of pages7
Pages (from-to)2055-2061
<mark>Original language</mark>English


Syntheses and structures of mer-[FeCl3(pyrazole)(3)] (1), mer-[FeCl3(N-methylimidazole)(3)] (2), mer-[FeCl3(terpy)] (3) (terpy = 2,2': 6',2"-terpyridine), mer-[FeCl3(tptz)] (4) (tptz=2,4,6-tris(2-pyridyl)-1,3,5-triazine) and trans -[FeCl2(3-methylpyrazole)(4)]Cl (5) are reported. The structures demonstrate intramolecular N-H...Cl; imramolecular C-H... Cl; and intermolecular N-H...Cl interactions. Syntheses and analytical data are also reported for [FeCl3(imidazole)(4)] (6), but crystals suitable for X-ray study were not obtained. (C) 2002 Elsevier Science Ltd. All rights reserved.