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Syntheses, structural studies and spectroscopic characterisation of pyridyl–phthalimide complexes of fac-(CO)3ReI-diimines

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Syntheses, structural studies and spectroscopic characterisation of pyridyl–phthalimide complexes of fac-(CO)3ReI-diimines. / Thorp-Greenwood, Flora L. ; Coogan, Michael; Hallett, Andrew J. et al.
In: Journal of Organometallic Chemistry, Vol. 694, No. 9-10, 2009, p. 1400-1406.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Thorp-Greenwood, FL, Coogan, M, Hallett, AJ, Laye, RH & Pope, SJA 2009, 'Syntheses, structural studies and spectroscopic characterisation of pyridyl–phthalimide complexes of fac-(CO)3ReI-diimines', Journal of Organometallic Chemistry, vol. 694, no. 9-10, pp. 1400-1406. https://doi.org/10.1016/j.jorganchem.2008.12.048

APA

Thorp-Greenwood, F. L., Coogan, M., Hallett, A. J., Laye, R. H., & Pope, S. J. A. (2009). Syntheses, structural studies and spectroscopic characterisation of pyridyl–phthalimide complexes of fac-(CO)3ReI-diimines. Journal of Organometallic Chemistry, 694(9-10), 1400-1406. https://doi.org/10.1016/j.jorganchem.2008.12.048

Vancouver

Thorp-Greenwood FL, Coogan M, Hallett AJ, Laye RH, Pope SJA. Syntheses, structural studies and spectroscopic characterisation of pyridyl–phthalimide complexes of fac-(CO)3ReI-diimines. Journal of Organometallic Chemistry. 2009;694(9-10):1400-1406. doi: 10.1016/j.jorganchem.2008.12.048

Author

Thorp-Greenwood, Flora L. ; Coogan, Michael ; Hallett, Andrew J. et al. / Syntheses, structural studies and spectroscopic characterisation of pyridyl–phthalimide complexes of fac-(CO)3ReI-diimines. In: Journal of Organometallic Chemistry. 2009 ; Vol. 694, No. 9-10. pp. 1400-1406.

Bibtex

@article{fdcbbdd6f9e84cd4bec420ea83ab3a1d,
title = "Syntheses, structural studies and spectroscopic characterisation of pyridyl–phthalimide complexes of fac-(CO)3ReI-diimines",
abstract = "The mono-dentate ligands, 3-aminomethyl-N-phthalimido-pyridine (L1) and 3-amino-N-phthalimido-pyridine (L2), were synthesised using a solvent-free melt method. These ligands were then used to access three pairs of functionalised luminescent ReI complexes of the generic type fac-{Re(CO)3(diimine)(Ln)}(BF4). The photophysical studies show that the visible emission from each of the six complexes is 3MLCT at room temperature. Within each pair of complexes the precise energy of the emission was subtly dependent upon the axial ligand, Ln with luminescence lifetimes in the range 121–288 ns.",
author = "Thorp-Greenwood, {Flora L.} and Michael Coogan and Hallett, {Andrew J.} and Laye, {Rebecca H.} and Pope, {Simon J. A.}",
year = "2009",
doi = "10.1016/j.jorganchem.2008.12.048",
language = "English",
volume = "694",
pages = "1400--1406",
journal = "Journal of Organometallic Chemistry",
publisher = "Elsevier",
number = "9-10",

}

RIS

TY - JOUR

T1 - Syntheses, structural studies and spectroscopic characterisation of pyridyl–phthalimide complexes of fac-(CO)3ReI-diimines

AU - Thorp-Greenwood, Flora L.

AU - Coogan, Michael

AU - Hallett, Andrew J.

AU - Laye, Rebecca H.

AU - Pope, Simon J. A.

PY - 2009

Y1 - 2009

N2 - The mono-dentate ligands, 3-aminomethyl-N-phthalimido-pyridine (L1) and 3-amino-N-phthalimido-pyridine (L2), were synthesised using a solvent-free melt method. These ligands were then used to access three pairs of functionalised luminescent ReI complexes of the generic type fac-{Re(CO)3(diimine)(Ln)}(BF4). The photophysical studies show that the visible emission from each of the six complexes is 3MLCT at room temperature. Within each pair of complexes the precise energy of the emission was subtly dependent upon the axial ligand, Ln with luminescence lifetimes in the range 121–288 ns.

AB - The mono-dentate ligands, 3-aminomethyl-N-phthalimido-pyridine (L1) and 3-amino-N-phthalimido-pyridine (L2), were synthesised using a solvent-free melt method. These ligands were then used to access three pairs of functionalised luminescent ReI complexes of the generic type fac-{Re(CO)3(diimine)(Ln)}(BF4). The photophysical studies show that the visible emission from each of the six complexes is 3MLCT at room temperature. Within each pair of complexes the precise energy of the emission was subtly dependent upon the axial ligand, Ln with luminescence lifetimes in the range 121–288 ns.

U2 - 10.1016/j.jorganchem.2008.12.048

DO - 10.1016/j.jorganchem.2008.12.048

M3 - Journal article

VL - 694

SP - 1400

EP - 1406

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 9-10

ER -