Research output: Contribution to Journal/Magazine › Journal article › peer-review
| <mark>Journal publication date</mark> | 28/10/2013 |
|---|---|
| <mark>Journal</mark> | Organometallics |
| Issue number | 20 |
| Volume | 32 |
| Number of pages | 4 |
| Pages (from-to) | 5705-5708 |
| Publication Status | Published |
| Early online date | 20/05/13 |
| <mark>Original language</mark> | English |
The ferrocene-based bis(phosphinoamide) fc(NHPiPr 2)2 (where fc = 1,1′-ferrocenyl) has been synthesized and coordinated to scandium via alkane elimination. The subsequent reaction of fc(NPiPr2)2ScCH 2SiMe3(THF) with H2 yields a dinuclear scandium hydride species wherein the scandium centers are bridged by both hydride and phosphinoamide fragments.